微合金钢中第二相临界转换尺寸的研究.pdfVIP

A4 微合金钢中第二相临界转换尺寸的研究2 刘文庆，朱晓勇，钟柳明，王晓姣 （上海大学微结构研究重点实验室,上海 200444 ） 摘要：Nb-Mo-V 微合金钢在 1200℃固溶淬火，在不同的温度（500℃、550℃、600℃、650℃）回火4h 或在 650℃回火不同 时间，根据硬度曲线判断回火 4h 时析出强化机制发生转换的温度和在 650℃回火时析出强化机制发生转换的时间，利用三 维原子探针测量微合金钢析出强化机制发生转换时析出物的等效半径在 1.0nm 左右。根据第二相强化理论，认为共格应变强 化主导切过机制，计算得到 Nb-Mo-V 微合金钢中第二相强化机制临界转换半径约为 1.0nm，与三维原子探针测量得到的结 果很吻合。用共格应变强化切过机制可以很好地预测析出强化作用最显著时析出相的尺寸。 关键词：三维原子探针， 微合金钢，临界转换半径，第二相 Study on the Critical Transition Radius of Second Phase in Micro-alloyed Steel Liu Wenqing, Zhu Xiaoyong, Zhong Liuming, Wang Xiaojiao (Key Laboratory for Advanced Micro-Analysis, Shanghai University, Shanghai 200444, China) Abstract: Nb-Mo-V micro-alloyed steels were tempered for 4h at different temperature (500℃、550℃、600 ℃、650℃) or for different time at 650 ℃ after solution treatment at 1200 ℃ for 0.5h. The temperature and time that the transition of precipitate strengthening mechanium occurred could be ascertained by the temperature-hardness curve and time-hardness curve, the critical transition size of precipitates in micro-alloyed steel was determined as about 2.0nm by three dimensional atom probe (3DAP). Based on the precipitate strengthening theory and shearing mechanism dominated by coherency strengthening, the critical transition size of precipitates in Nb-Mo-V micro-alloyed steel was calculated as about 2.0nm, which was in agreement with the value measured by 3DAP. It indicates that the size of second phase can be predicted well by the precipitate strengthen theory when the precipitation stengthening function is the most apparent. Keywords: three dimensional atom probe (3DAP);micro-alloyed steel; critical transition radius; second phase 1 前言 第二相强化是钢中主要的强化方式。根据第二相颗粒与滑移位错的的交互作用机制，可以得到两种不 同的强化机制：位错切过第二相的切过机制；位错绕过第二相颗粒并留下环绕颗粒位错环的 Orowan 机制。第二相尺寸很小而与基体保持较好的共格关系时，容易变形，此时切过机制起主导作用，强化