PLLA%2fβ-TCP纳米复合支架的制备及性能研究.pdf

Abstract Inthis was chemical andthereaction thesis，nano-{3-TCPpreparedby precipitation of the andtheconcentration systemCa(N03)2’4H20／(NHa)2HP04．BycontrollingpH ratioof was thereis totheXRD reactants，nano-13-TCPgot，but impurityphaseaccording sizeis328nm the size average spectra．Theparticle byusingparticleequipment．Acording tothebimodal sizedistributionandtheserious particle particleagglomeration，the isnotideal．Inorderto theuniform sizedistributionandsolvethe preparation get particle triedtoreducethereaction PEG agglomerationproblems，we temperature，adddispersant and PEG／CamolarratioandmolecularofPEGinthereaction adjust weight system theconcentrationofthe molar CaCl2／Na3P04。Bycontrolling reactants，PEG／Caratio， PEGmolecularandcharacterizedXRDand canfindthatwhen weight by TEM，we PEG／Camolarratiowas molecularwas1 4，PEG 0000，calcination weight temperature was900。Cfor sizewas 289nmandthe were 3h，the nano一13-TCPparticle only particles distributedandhaduniform evenly shape． Onthis nano／microstructureof scaffoldswith basis，the PLLA／13-TCPcomposite different ratiowas induced method 13-TCP preparedbythermally phaseseparation usedSEMtoobservethe successfully．We micro-topography,so