泡沫凝胶性质的几种影响因素_陈启斌[2].pdfVIP

: 1006-3080( 2007) 01-0071-04 1 2 2 陈启斌 , 马宝歧, 倪炳华 ( 1. 华东理工大学化学系, 上海200237; 2. 西安石油大学化学与化工学院, 西安710065) : 泡沫凝胶是由含 发泡剂聚合物和交联剂的溶液在气体作用下发泡形成的, 它可以通 过与制取普通水基泡沫相似的方法得到研究了聚丙烯酰胺( PAM) 浓度和气体流量对泡沫质量 ( ) 和气泡尺寸的影响结果表明: 泡沫凝胶的值随PAM 的浓度和气体流量的增加而增大; 值 超过0. 86 时其气泡仍接近于球形; 泡沫凝胶的气泡平均尺寸随PAM 浓度的增大而增加, 且浓度 越大增加的趋势越明显; 泡沫凝胶的气泡平均尺寸随气体流量的增加而增加另外, 还研究了泡沫 凝胶体系的稳定性随温度的变化及存放时间对气泡尺寸的影响, 可以证实, 在30 以下, 泡沫凝胶 的稳定性较好, 高于35 时, 其稳定性变差; 存放时间对泡沫凝胶的气泡尺寸影响非常明显 : 泡沫凝胶; 泡沫质量; 聚丙烯酰胺; 交联剂; 水基泡沫 : O631 : A Effectsof Several FactorsonthePropertiesof aFoamedGel 1 2 2 CH EN Qi-bin , MA Bao-qi , NI Bing-hua (1. Dep artment of Chemistry , East China niversity of Science and Technology , Shanghai 200237, China; 2. School of Chemistry and Chemical Eng ineering, X ian Petroleum niversity , Xian 710065, China) Abstract: A foame gel is generate in a cross-linking polymer solution containing a foaming agent un er acration. The metho use is similar to those for general aqueous foam generation. This w ork inves- tigate the effects of the ifferent concentrations of polyacrylami e an the gas flow rates on the foam qua-l ity ( ) an the air bubble size respectively. Results show that value increases w ith the concentration of PAM an gas flow rate, an the air bubble still appeare as a ball w hen value reaches above 0. 86. On one han , the mean size of air bubble increases w ith the concentration of PA M, the higher the concentra- tion, the sharper the increasing; on the other han , the mean size of bubble increases w ith the gas flow rate. In a ition, the variation of the stability of a foame gel w ith temperature an the effect of time on bubble