ZK60镁合金的组织与腐蚀性能研究.pdfVIP

摘 要 摘 要 本文采用光学显微镜、扫描电镜、能谱分析和 X 射线衍射分析，以及静态失重法、 电化学测试和力学性能测试等手段，系统研究了铸态ZK60 合金不同热处理状态的组 织与腐蚀性能，以及变形 ZK60 合金不同热处理状态的腐蚀性能与力学性能，并进一 步探讨了稀土 Nd 对 ZK60 合金组织和腐蚀性能的影响。 实验结果表明：铸态 ZK60 合金由 α-Mg 固溶体和晶界的MgZn 相和 MgZn2 相组 成，铸态合金因第二相偏析严重且晶界不连续分布，耐蚀性较差。时效使大量的第二 相沿晶界析出，晶粒更为细小，其连续网状晶界可以有效提高耐腐蚀性能；均匀化处 理使 MgZn 相固溶入基体，且晶界断续，其耐蚀性最差；固溶加人工时效合金的晶界 大多为颗粒状或短杆状，不能阻挡腐蚀进行，耐蚀性较差。 轧制时效合金比轧制退火合金晶界析出物多，增多了微电偶腐蚀数目，降低了其 腐蚀性能。商用变形 ZK60 合金存在择优取向。时效和固溶加人工时效后腐蚀速率与 原始退火合金差别不大，同一温度时效时间越长，耐腐蚀性能越差。人工时效使合金 的屈服强度大幅度提高，固溶加人工时效处理使合金的抗拉强度和屈服强度都有所下 降。 ZK60-1%Nd 合金由 α-Mg 基体和晶界的 MgZn 相、MgZn 相和 Mg Nd 相组成。 2 12 加 Nd 后晶粒更为细小，晶界结构连续和紧实，晶界宽而明显，大量带状或链状组织 相互连接成网状，Nd 的加入大大提高了ZK60 合金的耐腐蚀性能。 关键词：ZK60 镁合金，腐蚀，热处理，微观组织 I ABSTRACT ABSTRACT In this paper, the microstructure and corrosion resistance of as-cast ZK60 alloy in different heat treatment states, and the effect of heat treatment on corrosion resistance and mechanical properties of rolled ZK60 alloy were studied.The influence of rare earth-Nd on microstructure and corrosion resistance of ZK60 alloy were also investigated systematically by OM, SEM, EDS, XRD, tests of static weight-loss, as well as tests of polarization curves and mechanical properties respectively. The results indicated that as-cast ZK60 alloy was composed of α–Mg solid solution, MgZn and MgZn2 phases. This alloy shows poor corrosion resistance for its serious segregation and discontinuous boundary. Aging treatment produced a large number of precipitates along grain boundaries, which made the grains smal