3Cr低合金钢在含饱和CO2的NaCl溶液中的腐蚀电化学行为.pdfVIP

25 1 Vol.25 No.1 2 0 1 1 2 CHINESE JOURNAL OF MATERIALS RESEARCH February 2 0 1 1 3CrCO NaCl 2 ∗ (Æ Æ 100083) CO2 NaCl pH 3Cr : NaCl pH (2, 3.9) , , ; pH (6.5) , , , NaCl pH 3Cr NaCl pH , , , 3Cr , pH, , TG172 1005-3093(2011)01-0039-06 Effect of pH on the Corrosion and Electrochemical Behavior of 3Cr Steel in CO2 Saturated NaCl Solution JIA Zhijun DU Cuiwei∗∗ LIU Zhiyong GAO Jin LI Xiaogang (Advanced Material Technology Institute, University of Science and Technology Beijing, Beijing 100083) * Supported by National High Technology Research and Development Program of China No.2009AA063405-04. Manuscript received November 1, 2010; in revised form January 3, 2011. ** To whom correspondence should be addressed, Tel:(010514, E–mail :ducuiwei@ ABSTRACT The effect of pH value of NaCl solution on the corrosion and electrochemical behaviors of 3Cr low-alloy steel was investigated by electrochemical technique and SEM technique. The results showed that the pH value of NaCl solution had great effect on the structure of corrosion product. The corrosion scale had a monolayer and map cracking appears when pH=2 and 3.9. The corrosion product film had a triple structure when pH=6.5. The pH of corrosion media also had apparent effect on the electrochemical behaviors of the Cr low-alloy steel. With pH increasing, the main cathodic reaction of electrode process altered, resulting in the negative moving of the corrosion potential, and by the increasing of the charge transfer resistance, the corrosion current density decreased. KEY