几种马来酸氢酯类分光晶体的生长及动力学研究.pdfVIP

Material Sciences 材料科学, 2011, 1, 30-35 doi:10.4236/ms.2011.11006 Published Online April 2011 (/journal/ms/) Growth and Kinetics of Three Esters of Maleate Acid * Yuyu Liang, Shukun Lin College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou Email:lsk195625@ Received: Mar. 8th, 2011; revised: Apr. 6th, 2011; accepted: Apr. 7th, 2011. Abstract: Tetradecyl hydrogen maleate (THM), hexadecyl hydrogen maleate (HHM) and octadecyl hydro- gen maleate (OHM)) were successfully grown by the method of slow cooling in solution. The solubility curves in benzene were studied. The results showed that with the increase of the temperature, solubility of the three crystals became larger. At the same temperature, the solubility of THM is the largest, rather than the HHM and OHM. The kinetics experiments had used the method of dynamic loop, measuring the growth rate of ( 03 1 ) and ( 111 ).The results showed that: the relevant growth rates were decreased and the diffusion re- sistance of atoms to enter the lattice position became bigger with the increasing of long carbon chains. The link between the difficulty of crystal growth along the (010) direction and the crystal structures was estab- lished. The growth rates reduced with the longer carbon chains by the comparative of THM, HHM and OHM. The series of work has instructed the research of X-ray dispersing crystal of maleate acid. These three title esters should be a good candidate for homologous X-ray analyzer crystals. Keywords: Growth From Solutions; Crystal Growth Kinetics; Crystal Structure; X-Ray Analyzer Crystal 几种马来酸氢酯类分光晶体的生长及动力学研究