从铜转炉白烟灰中回收有价金属技术的发展与展望的论文.docVIP

从铜转炉白烟灰中回收有价金属技术的发展与展望 陈龙 (中南大学冶金科学与工程学院，高级工程人才试验班，0505110124) 摘要：铜冶炼过程产生的白烟灰为目前工业上极具代表性的含铜废弃物之一，其中不但含有Cu、Zn、Pb、Ni、Co及In、Ge有价元素，同时含有砷等有害元素。这种废弃物不及时处理不但会造成严重的环境污染，也造成了资源的浪费。随着我国经济的快速发展，对于各种资源的依存度在加大，造成了近年来有色金属及稀有金属价格的暴涨。从工业废弃物中回收有价金属，加速二次资源的利用，对于满足我国国民经济发展的需要具有实际意义和紧迫性。 经过系统地研究白烟灰中有价金属元素的浸出、分离及回收工艺，优化了白烟灰中有价金属浸出工艺，提出合理的浸出工艺流程，为实现铜冶炼白烟灰中有价金属元素的综合回收利用进一步工业化提供了理论和实践基础。同时对于环境保护及资源的综合利用也具有十分重要的意义。 关键词：铜冶炼 白烟灰 有价金属 资源浪费 优化 ABSTRACT ：White ash produced in copper convecting process generally composed of various elements such as copper，zinc，nickel，cobalt，iron，arsenic，indium，rhenium，and SO on in wide concentration ranges，is the main solid waste in copper smelting．Considering both valuable and harmful elements contained in the ash，resources waste and severe environmental pollution will be caused if the ash were not handled in time．With rapid development of economy in China，dependence degree to some resources is increasing，resulting in the soaring price of valuable and rare metals．Therefore，it is meaningful and necessary to recover valuable metals from the industrial wastes and to accelerate utilization of second resources，such as recovering Koppel zinc etc．from the copper—smelting white ash． Passed a process of separating and recovering valuable metals from copper-smelting white ash by acid leaching。 Leaching process has been optimized by leaching at different conditions。The mentioned studies provide certain theoretical foundations for the industrialization of treating copper-smelting ash．Meanwhile，considering1imited resources in the world and serous contamination to the environment caused by the ash，it is significant to process the copper-smelting sulfite ash． KEYWORDS:copper convecting White ash the valuable metals wasting of resources optimize 前言:长期以来，我国铜资源不能满足国内消费需求，供需缺口较大，需要通过国际市场加以平衡，为此国家每年要花大量外汇。为了确保国民经济发展对铜产品的消费需要，保障铜资源的长期稳定安全供应，研究制定我国铜资源的发展战略已势在必行，但是在制定铜资源战略之前必须了解我国的铜资源现状。我国是世界铜资源大国