_环糊精聚合物微球的合成与表征.pdfVIP

277 精 细 化 工 V ol. 27, N o. 7 2 0 1 0 7 FINE CHEM ICALS July 2 0 1 0 李仲谨, 杨 威, 王培霖, 刘 艳, 田晓静 ( , 71002 1) : ( CD ) , ( ECH ) , ( CDP ) 5 L16 ( 4 ) , X , : n( ECH ) /n(CD ) = 15 12 g 60 mL 70 5 h; : n( E CH ) /n(CD ) ; CDP, , , , : ; ; ; ; : TQ 314. 2 : A : 1003- 5214 ( 20 10) 07 - 0692- 04 SynthesisandCharacterization ofCyclodextrin PolymerM icrospheres L I Zhongin, YANG W e,i WANG Pe ilin, L IU Y an, T IAN X iaoing (Key Laboratory of Auxiliary Chemistry Technologyf or Chem ical Industry,M inistry of Education, Shaanxi niversity of Science Technology,X i an 71002 1, Shaanx,i China) Abstract: Cyclodextrin po lym er ( CDP ) m icrospheres w ere syn thesized in the inverse emu lsion w ith 5 cyc lodex trin as m ateria l and epich lorohydrin as crosslink ing agent. The L16 ( 4 ) orthogona l test w as used to obta in op tmi um techno log ical param eters. T he po lym erm icrospheresw ere character ized by scan e lectron m icroscope, FT IR spectroscopy, therm ograv mi etric ana lysis ( TGA ) and Xray diffraction ( XRD) . T he results ind icated that the best rat io of ep ichlorohydrin to cyclodex trin w as 15!1, the quantity of em ulsif ier w as 12 g, the quant ity of kerosene w as 60 mL, em ulsifying tem perature w as 70 and the emu lsify ing tmi e w as 5 h. The in fluencing factors w ere em ulsify ing tem perature, em ulsify ing tmi e, the quant ity of em ulsifier, the ratio o f epichlorohydrin to cyclodex trin, w eigh