固相微萃取_高效液相色谱联用分析环境水样中的痕量多环芳烃.pdfVIP

2003 11 Vol. 21 No. 6 November 2003 Chi nese ! Journal of Chromatograp hy 599~ 602 陶敬奇, 王超英, 李碧芳, 李攻科 ( , 510275) : (S ME)(H LC) 8 8 0002~ 0180 g/ L, (RSD, n= 6) 44% ~ 122% , [ b] , 7 911% ~ 1158% , RSD( n= 3) 36% ~ 188% , :; ; ; : O658 :A :2003) Determination of Trace Polycyclic Aromatic Hydrocarbons in Environmental Waters by SolidPhase Microextraction Coupled with Hi h Performance Liquid Chromato raphy TAO Jingqi, WANG Chaoying, LI Bifang, LI Gongke ( School of Chemistry and Chemical Engineering , Sun Yatsen Univ ersity, Guangz hou 510 75 , China) Abstract: A rapid method for the determination of trace polycyclic aromatic hydrocarbons ( AHs) in environmental waters by solidphase microextraction ( S ME) coupled with high performance liquid chromatography ( H LC) was developed. The experimental conditions of S ME, such as extraction time, extraction temperature, desorption time, desorption solution, desorption mode and the analytical conditions of H LC were optimized. The detection limits for eight AHs were from 0002 to 0180 g/ L, and the relative standard deviations ( RSDs) were from 44% to 122%. T he method was used for the determination of trace AHs in river water. T he recoveries were from 911% to 1158% ex cept for benzo[ b] fluoranthene. T he RSDs were from 36% to 188% . The method is fast, conve nient, sensitive, solventfree, and suitable for the determination of trace AHs in environmental wa ters. Key words: solidphase microextraction; high performance liquid chromatography; polycyclic aromatic hydrocarbons; water ( AHs) ,