Selection of Chelated Fe(III)Fe(II) Catalytic Oxidation Agents for Desulfurization Based on Iron Complexation Method.pdfVIP
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Selection of Chelated Fe(III)Fe(II) Catalytic Oxidation Agents for Desulfurization Based on Iron Complexation Method.pdf
ChinaPetroleum ProcessingandPetrochemicalTechnology
ScientificResearch 2014,Vo1.16,No.2,PP50—58 June30,2014
SelectionofChelatedFe(III)/Fe(II)CatalyticOxidation
AgentsforDesulfurizationBasedonIron
ComplexationM ethod
LuoYing,;LiuYouzhi’;QiGuisheng;GuoHuidong;ZhuZhengfeng’
(.ShanxiProvinceKeyLaboratoryofHigee—OrientedChemicalEngineering,NorthUniversityofChina,
Taiyuan030051,2.ResearchCenterofShanxiProvinceonHighGravityChemicalEngineering
Technology,NorthUniversiytofChina,Taiyuan030051)
Abstract:Optimizationoffactorsinfluencingtheexperimentsonreactionsinvolving8differentchelatingagentsandsol—
ubleFe(III)F/e(II)saltswascarriedouttoyieldchelatedironcomplexes.Acombinationofoptimizedinfluencingfactors
hasresultedinaFechelatingcapacityoftheiron-baseddesulfurizationsolutiontobeequalto6.83— 13.56g/Lataredox
potentialof0.185— .3.ThedesulfurizationperformanceofFe(III)/Fe(II)chelatingagentswasinvestigatedonasimulated
sulfur-containingindustrialgascomposedofH2SandN2inacross—flowrotatingpackedbed.Testresultshaverevealedthat
theproposediron—baseddesulfurizationsolutionshowedasulfurremovalefficiencyofover99% alongwithaFechelating
capacityexceeding1.35g/L.Thisdesulfurizationtechnologywhichhaspracticalapplicationprospectiscurrentlyinthe
phaseofcommercialscale-upstudy.
Keywords:hydrogensulfide;chelatediron;catalyticoxidation;factoranalysis;redox
1 IntrOducti0n b1Formationofelementalsulufrviathereactionofche一
1atedirononHS。:
Hydrogensulfidegasgeneratedduringpetroleum refin—
ing,naturalgasprocessing,citygasproductionandother H2S(g)一H2S(aq)
chemicalsynthesisprocesses,whichcancorrodemetallic
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