pdf - 二苯基噻吩活性氧量子产率杀虫活性及稳定性的研究.pdfVIP

中国农业科学 2006,39(1):81-87 Scientia Agricultura Sinica 二苯基噻吩活性氧量子产率、杀虫活性及稳定性研究 陈小军，徐汉虹，王玉健，胡 珊，张志祥，张耀谋 （华南农业大学昆虫毒理研究室／农药与化学生物学教育部重点实验室，广州 510642 ） 摘要: 【方法】以α- 三联噻吩（α-T）为对照，首次研究了二苯基噻吩活性氧量子产率、杀虫活性及稳定性。 【结果】二苯基噻吩紫外光照射280 min 后吸光度变化最大值为ΔA=0.438，α-T在200 min后吸光度变化值最大 ΔA=0.480；二苯基噻吩和 α-T对白纹伊蚊3 龄幼虫24h的LC -3 -1 -4 -1 50 值分别为9.18×10 µg·ml 和9.69×10 µg·ml ， 对小菜蛾3龄幼虫LC -1 -1 50 值分别为267.87 µg·ml 和 222.22 µg·ml ；二苯基噻吩和 α-T 在甲醇中半衰期为113.62 h 和10.65 h。二苯基噻吩量子产率与 α-T相当，对白纹伊蚊和小菜蛾具有较好的光活化毒杀作用，但稳定性好。 【结论】二苯基噻吩克服了光活化杀虫剂稳定性差而难以在田间推广使用等不足，在杀虫的同时又能催化降解残 留农药三唑磷，二苯基噻吩有广泛的开发和应用前景。 关键词：二苯基噻吩；量子产率；杀虫活性；稳定性 Study on Active Oxygen Quantum Yield, Insecticidal Activities and Stability of Diphenylthiophene CHEN Xiao-jun, XU Han-hong, WANG Yu-jian, HU Shan, ZHANG Zhi-xiang, ZHANG Yao-mou (Key Laboratory of Pesticide and Chemical Biology , Ministry of Education, Laboratory of Insect Toxicology, South China Agricultural University, Guangzhou 510642) Abstract: 【Objective 】Active oxygen quantum yield, insecticidal activities and stability of diphenylthiophene were compared to α-terthienyl in a study for the first time. 【Result 】The results showed that absorbency variety max of diphenylthiophene was 0.438 after ultraviolet irradiation for 280 min while α-terthienyl absorbency variety max was 0.480 after ultraviolet irradiation for 200 min. LC -3 -1 -4 50 value of diphenylthiophene and α-terthienyl against 3rd instar larvae of Aedes albopictus was 9.18 ×10 μg·ml and 9.69 ×10 μg·ml-1 after 24 h of