分散液相微萃取-气相色谱法测定水中的苯乙酮及其衍生物.docVIP

分散液相微萃取-气相色谱法测定水中的苯乙酮叶存玲，（河南师范大学化学学院，河南 新乡 453007）摘要：液相微萃取-气相色谱苯乙酮氯仿为萃取剂，乙腈为分散剂，考察了萃取剂和分散剂的种类及体积，溶液pH值及等因素对萃取效果的影响。该方法对的线性范围分别为0.5-100.0 μg L-1、0.9-100 μg L-1、1.0-100.0 μg L-1、0.7-100.0 μg L-1和0.8-100.0 μg L-16次重复测定的相对标准偏差0.3-0.6 μg L-1和2.5%~8.5%。该方法应用于自来水、地下水、泉水和湖水样品的分析测定，回收率在90.2-113.9%之间。液相微萃取气相色谱法苯乙酮及其衍生物Determination of hypnone derivatives in water samples by dispersive liquid-liquid microextraction-gas chromatography YE Cun-ling*, WANG He-ping, LIU Qing-ling, WANG Zhi-ke (School of Chemistry and Chemical Engineering, Henan Key Laboratory for Environmental Pollution Control, Key Laboratory for Yellow River and Huai River Water Environment and Pollution Control, Ministry of Education, Henan Normal University, Xinxiang Henan 453007) Abstract: A simple and efficient method known as dispersive liquid-liquid microextraction was demonstrated for the extraction of hypnone derivatives in real water samples prior to GC-FID. Several related parameters, including volumes and types of extraction reagent and dispersive reagent, pH and salinity of solution, that could affect the extraction efficiencies were also investigated and optimized. Under the optimum conditions, a linear range was obtained in the range of 0.5-100.0 μg L-1 for hypnone, 0.9-100.0 μg L-1 for 2-hydroxy acetophenone 1.0-100.0 μg L-1 for p-bromoacetophenone, 0.73-100 μg L-1 for p-acetylanisole and 0.77-100 μg L-1 for diphenyl ketone, respectively. The limits of detection (LODs) (S/N=3) values were in the range of 0.3-0.6 μg L-1. The relative standard deviations of five hypnone derivatives for six repeated determinations were in the range of 2.5%- 8.5%. The relative recoveries of the five analytes in tap, well, lake and fountain water samples were in the range of 90.2-113.9%. Keywords: Dispersive liquid-liquid microextraction; Gas chromatography; Hypnone derivatives; Water samples 苯乙酮及其衍生物均是医药中间体、有机合成的原料、香精香料，它们的过使用势必会在环境中大量残留，经过长时间的暴露分解成具有毒害的芳香化合物，将对环境和人畜安全产生威胁。因此建立对苯乙酮及其衍生物的分析检测方法是非常有必要的。目前对此类化合物的分析方法还很少见，