添加Nb对Zr-4合金在500 ℃过热蒸汽中耐腐蚀性能影响.pdfVIP

47 7 Vol.47 No.7 2011 7 865—871 ACTA METALLURGICA SINICA Jul. 2011 pp.865–871 Nb Zr–4 500 ∗ 1,2) 1) 1) 2) 1,2) 3) 3) 1) , 200072 2) , 200444 3) , 100088 Zr–4 0.1%—0.3%()Nb 500 /10.3 MPa , TEM SEM . , 500 /10.3 MPa 500 h , , Nb α–Zr , α–Zr Nb , ; Nb , Nb α–Zr (Fe+Cr) , Zr(Fe, Cr, Nb)2 , 2 , . , Nb, , TL341 A 0412−1961(2011)07−0865−07 EFFECT OF Nb ON THE CORROSION RESISTANCE OF Zr–4 ALLOY IN SUPERHEATED STEAM AT 500 YAO Meiyi 1,2) , LI Shilu 1), ZHANG Xin 1), PENG Jianchao 2) , ZHOU Bangxin 1,2) , ZHAO Xushan 3) , SHEN Jianyun 3) 1) Institute of Materials, Shanghai University, Shanghai 200072 2) Laboratory for Microstructures, Shanghai University, Shanghai 200444 3) General Research Institute for Nonferrous Metal, Beijing 100088 Correspondent: YAO Meiyi, associate professor, Tel: (021 E-mail: yaomeiyi@ Supported by National Natural Science Foundation of China (Nos and, High Technology Research and Development Program of China (No.2008AA031701), Natural Science Foundation of Shanghai (No.09ZR1411700) and Shanghai Leading Academic Discipline Project (No.S30107) Manuscript received 2011–03–03, in revised form 2011–03–21 ABSTRACT The corrosion resistance of Zr–4+xNb alloys (x=0.1—0.3, mass fraction, %) was investigated in a superheated steam at 500 and 10.3 MPa by autoclave tests. The microstructure of the alloys and fracture surface morphology of the oxide film formed on the alloys were observed