熔融碳酸盐燃料电池发电试验中气密封的研究.pdfVIP

熔融碳酸盐燃料电池发电试验中 气密封的研究 张瑞云，许世森，程健 中国华能集团清洁能源技术研究院有限公司，北京100098； Test Study on Gas Seals of Power Generation from Molten Carbonate Fuel Cells ZHANG Rui-yun ，XU Shi-sen ，CHENG Jian China Huaneng Clean Energy Research Institute，Beijing 100098 ； ABSTRACT ：The types and reasons of gas leaking of 1 引言 power generation from molten carbonate fuel cell (MCFC) have been analyzed and specific proposals are put forward 近些年来，燃煤电厂（火电厂）在发电及输 to solve the gas seal. Gas leaking from the MCFC 送电的过程中不断出现新的问题，例如夏天不断 electrolyte to the external environment can be effectively prevented by using the sealed plate and gasket with a 出现“电荒”，冬天要是出现大雪、冻雨等恶劣 certain assembly pressure. In addition, optimizing the matrix preparation process and the matching relationship 天气，输送电也不断出现新的挑战。面对这些日 between the matrix and the electrolyte could solve the gas 益突出的用电问题，使得我们开始思考，过于依 leaking risk inside the cell. The test shows that the single cell using the above program could keep good circuit 赖火力发电并不是长久之计，尤其是在我国这个 voltage above 1.1V for several cycles and can effectively solve the problem of gas leaking of power generation from 以煤为主要能源，火力发电占据绝对优势的情况 molten carbonate fuel cell (MCFC)1. 下，我们更应该谋求能源利用结构的多元化。 KEY WORD molten carbonate fuel cells (MCFC) single ： ； 燃料电池能够将燃料（天然气、煤制气等） cell ；fuel cell stack ；gas seals 中氢气借助于电解质与空气中的氧气直接转化 摘要：分析了熔融碳酸盐燃料电池在发电试验中气体泄 为电能，具有高效洁净的显著特点，被称为是继 漏的类型及原因，提出了解决气密封的具体方案。使用 密封框板、密封垫圈等，配合一定的装配压力，有效地 火力发电、水力发电、核能发电之后的第四大发 解决了气体从熔融碳酸盐燃料电池的电解质周边向外 界的泄漏；通过优化电解质隔膜的制备工艺及电解质隔