雙-三芽基半卡腙配位體以及其過渡金屬錯合物之合成探討.docxVIP

標題16點字、粗體（文章字體）中文：標楷體; 英文: Time New Roman 編號: 1 作者14點字Syntheses of bis-tridentate ligands with diaminoalkane α-chloroformylarylhydrazine and salicylaldehyde moietiesShih, M. H.(施美秀)*, Kuo, C. H.(郭沁宏), Xu, Y. Y.(許育源), 地址12點字、斜體Lin, T. T.(林姿婷), Chang, C. T.(張晉慈), Deng, W. H.(鄧偉秀)Department of Chemical and Materials Engineering, Southern Taiwan University, 關鍵字12點字Tel: 06-2533131 ext 3723; E-mail: meihsius@mail.stut.edu.twKeywords: α-Chloroformylarylhydrazine; Semicarbazides; Salicyaldehyde; Semicarbazones; Transition metal complexes主文12點字 α-Chloroformylarylhydrazine 1a-c contains two different functional groups. One is the strong nucleophile, and the other is a good electrophile. Therefore, it can react with several reagents to obtain diverse derivatives, which can be used as ligands for metal complexes. Besides, aliphatic diamines and salicylaldehydes can provide electron donor sites, N and O electron donors, separately. Therefore, α-chloroformyl- arylhydrazines 1a-c was first treated with diaminoalkanes 2-3 to give the corresponding semicarbazides 4a-4c, 5a-5c. Then, the semicarbazides 4a-4c, 5a-5c reacted with salicylaldehyde 6 to afford a serial of salicylaldehyde N, N’-alkane-bis (2-aryl)semicarbazones 7a-8c, which are expected to be bis-tridentate ligands and can coordinate with various transition metal ions to give the desired metal complexes.參考文獻格式12點字a: Ar = C6H5, b: Ar = p-CH3C6H4, c: Ar = p-CH3OC6H4; 2: n = 2; 3: n = 3References:1. Tas, E.; Kilic, A.; Durgun, M.; Kupecik, L.; Yilmaz, I.; Arslan, S. Spectroc. Acta Pt. A-Molec. Biomolec. Spectr. 2010, 75, 811-8182. Hong, M.; Yin, H. D.; Chen, S. W.; Wang, D. Q. J. Organomet. Chem. 2010, 695, 653-662.3. Shit, S.; Rosair, G.; Mitra, S. J. Mol. Struct. 2011, 991, 79-83. 編號: 2 雙-三芽基半卡腙配位體以及其過渡金屬錯合物之合成探討Shih, M. H. (施美秀)*, Tey, Z. B. (鄭振邦), Lin, K. W. (林洸偉), Yang, Y. S. (楊育陞)南台科技大學 化學工程與材料工程系, Tel:06-2533131ext.3723; E-mail: mailto:meihsius@mail.stut.edu.twmeihsius@mail.stut.edu.twKeywords: α-氯醯基芳香肼; 柳醛; 雙-三芽基半卡腙