非晶态合金Ru基催化剂在苯选择加氢中应用进展.pdfVIP

2011 Chinese Journal of Catalysis Vol. 32 No. 1 文章编号: 0253-9837(2011)01-0001-16 国际版DOI: 10.1016/S1872-2067(10)60154-4 综述: 1~16 非晶态合金Ru 基催化剂在苯选择加氢中的应用进展 孙海杰, 郭 伟, 周小莉, 陈志浩, 刘仲毅, 刘寿长 郑州大学化学系, 河南郑州 450001 摘要：化学还原法制备的非晶态合金 Ru 基催化剂融合了纳米粒子和非晶态合金的结构特征, 在苯选择加氢反应中表现出高活 性和高环己烯选择性; 尤其是负载型非晶态合金 Ru 基催化剂, 具有贵金属利用率高和易于工业化等优点, 有着明显的竞争优势. 本文综述了苯选择加氢的热力学和动力学特征, 非晶态合金催化剂结构和组成及其对催化性能的影响; 总结了催化工艺条件、 催化剂可调变性和中试成果, 并展望了该技术的发展趋势. 关键词：苯; 选择加氢; 环己烯; 非晶态合金; 钌基催化剂 中图分类号：O643 文献标识码：A Progress in Ru-Based Amorphous Alloy Catalysts for Selective Hydrogenation of Benzene to Cyclohexene * SUN Haijie, GUO Wei, ZHOU Xiaoli, CHEN Zhihao, LIU Zhongyi , LIU Shouchang Department of Chemistry, Zhengzhou University, Zhengzhou 450001, Henan, China Abstract: Ru-based amorphous alloy catalysts prepared by the chemical reduction method have high activity and excellent cyclohexene selectivity due to their structure that has the merits of amorphous alloys and nano-particles. In particular, the supported catalysts have the advantages of better utilization of the Ru noble metal and ease of use in industry. The thermodynamics and kinetics for selective hydrogena- tion of benzene to cyclohexene over these catalysts, and the influence of the structure and composition of the catalysts were described. The reaction conditions, ability to modify the catalysts, and results of pilot tests were emphasized. Directions in this field for future research were suggested. Key words: benzene; selective hydrogenation; cyclohexene; amorphous alloy; ruthenium-based catalyst 由苯出发经环己烯制备尼龙 6 和尼龙 66 比经环