ATRP论文：聚偏氟乙烯ATRP法改性.docVIP

ATRP论文：聚偏氟乙烯的ATRP法改性 【中文摘要】本论文通过铁盐催化AGET ATRP (Atom Transfer Radical Polymerization with Activators Generated by Electron Transfer)和常规ATRP法分别对聚偏氟乙烯和聚偏氟乙烯膜进行了直接接枝改性,使得聚偏氟乙烯具备了一些特殊的性能,从而扩大了聚偏氟乙烯膜的应用范围。主要研究内容和结果如下:(1)体系一:空气存在下铁盐催化AGET ATRP法改性聚偏氟乙烯。该体系采用铁盐催化AGET ATRP法直接对聚偏氟乙烯进行了接枝改性,以甲基丙烯酸甲酯(MMA)和甲基丙烯酸聚乙二醇单甲醚酯(PEGMA)为聚合单体,以FeCl3·6H2O为催化剂、三苯基膦(PPh3)为配体、抗坏血酸(VC)为 【英文摘要】In this thesis, modification of poly(vinyliene fluoride) (PVDF) and PVDF microfiltration (MF) membranes using activators generated by electron transfer (AGET ATRP) mediated by iron catalyst and normal ATRP were demonstrated, respectively. The modified PVDF has some special functions, which facilitates wider application of PVDF. The works can be summarized as follows:(1) System I: A novel approach to modify PVDF via iron-mediated AGET ATRP. Iron-mediated atom transfer radical polymerization using activators generated by electron transfer (AGET ATRP) directly from the secondary fluorine atoms on the PVDF backbone, using methyl methacrylate (MMA) and poly(ethylene glycol) methyl ether methacrylate (PEGMA) as the monomers, FeCl3?H2O as the catalyst, PPh3 as the ligand and vitamin C as the reducing agent, was demonstrated in the presence of limited amounts of air. The successful syntheses of the corresponding graft copolymers PVDF-g-PMMA and PVDF-g-PPEGMA were characterized by 1H nuclear magnetic resonance (1H NMR), Fourier transform infrared (FT-IR) and X-ray photoelectron spectroscopy (XPS), respectively. The graft copolymers PVDF-g-PPEGMA can be readily cast into porous hydrophilic microfiltration (MF) membranes by phase inversion in an aqueous medium. The morphologies were characterized by scanning electron microscopy (SEM). The surface and bulk hydrophilicity were evaluated on the basis of static water contact angle and the steady adsorption of Bovine serumal albumin (BSA). All these results demonstrate that both hydrophilicity and fouling resistance of the PVDF membrane can be improved.(2) System II:Surfa