二元非均匀体系非线性动力学扩散模型相关性.pdfVIP

b Vol No ACTA METALLURGICA SINICA Mar pp noSZdBhOIad tsy zx vwu LwLhUXVL p i YqXxerqWxfuV Fick qd CahnHilliard qvWqXx erxfuxGZWqVZiqxl m Q V TK Mxfu CahnHilliard qvzdbv nm W MoV n Wq Fick qd CahnHilliard qvYUqdxfuekxGMq iWqfqiWUqdeMiWqMxfu qXxerqxfuUqd rT TBTG WPF A Wq CORRELATION OF THE NONLINEAR KINETICS DIFFUSION MODELS IN BINARY NONUNIFORM SYSTEM CAO Baosheng ZHANG Zhipeng LEI Mingkai Surface Engineering Lab oratory Scho ol of Materials Science and Engineering Dalian University of Technology Dalian Correspondent LEI Mingkai pr ofessor Tel Email surfengd luteducn Supported by Teaching and R esearch Award Pr ogr am for Outstanding Young Pr ofessors in Higher Education Institutions of Ministry of Educations of China Manuscript received in revised form ABSTRACT Correlation of the nonlinear kinetic discrete mo del for diusion in binary nonuniform system and Fick s laws and CahnHilliard equation was discussed The diusion asymmetry co ecients m and the ordering energy V in the nonlinear kinetics discrete mo del are the main inuencing factor due to the strong concentration dep endence of the diusion co ecient in the binary nonuniform system The concentration proles of MoV multilayers with mo dulation wavelengths and nm were calculated by the nonlinear kinetic discrete mo del and CahnHilliard equation It is found that Fick s laws CahnHilliard equation and the nonlinear kinetic discrete mo del are all valid for description of wo formers increase gradually with decreasing