卤代芳烃胺基化反应的研究进展.pdfVIP

30 6 ( ) Vol.30 No. 6 2009 12 Journal of Qingdao University of Science and Technology(Natural Science dition) Dec.2009 :2009) 1 2 1 , , ( 1. , 266042; 2. , 621900) : 钯催化卤代芳烃胺基化反应是形成CAr N 的重要方法以卤代芳烃为线索,对 钯催化偶联胺化反应的研究进展和胺化反应 合成化合物到合成高分子的过渡进行了综 述,介绍了本课题组运用胺化反应合成高性能聚合物聚亚胺酮和聚亚胺醚酮的相关研究 : 卤代芳烃;钯催化胺化反应; 聚亚胺酮 : O 625.63 : A Progress in Palladiumcatalyzed Amination of Aryl Halides 1 2 1 LIN Runxiong , CHANGGuanjun , UN Lishui ( 1. ngineering Research Center of High Performance Polymer and M olding T echnology, Ministry of ducation, Qingdao University of Science and Technology, Qingdao 266042, China; 2. Research Center of Laser Fusion, China Academy of ngineering Physics, Mianyang 621900, China) Abstract: As an important method to form CAr N by palladiumcatalyzed amination of aryl halides,the research progress in palladiumcatalyzed amination is reviewed by using aryl halides as starting materials to synthesize compounds and polymers. Our works on synthesis of highperformance poly( imino ketone) s and poly(imino ether ketone) s are introduced. Key words: aryl halides; palladiumcatalysis amination; poly(imino ketone) CAr N , , 2005 , , [ 512] CAr N Ulmann 1 SNAr , , , , , , CAr N , , , , ,