采用循环伏安法的研究微孔型多孔炭电极电容特性.pdfVIP

中国有色金属学报 第 16 卷第 1 期 2006 年 1 月 Vo l. 16 No. 1 The Chinese Journal of Nonferrous Metals Jan. 2006 文章编号: 1004 一 0609(2006)01 - 0164 - 06 采用循环伏安法研究微孔型多孔炭电极的电容特性① 张琳，刘洪波 (湖南大学材料科学与工程学院，长沙 410082) 摘 要:以盼隆树脂为原料， KOH 为活化剂，制备出 3 种不同孔径分布的微孔型多孔炭(孔径;:;;;2 nm) 。在低温 氮气吸附法测定 BET 比表面积和孔结构的基础上，采用循环伏安法考察了这 3 种微孔型多孔炭作电极的双电层 电容器CEDLC) 的电容特性。实验结果表明，微孔型多孔炭作电极的 EDLC 的电容特性是:在低扫描速率下，其循 环伏安曲线达到电容平台后在高电压(士1. 0 V) 附近出现峰电容;延长在电解液中的浸渍时间，电极的比电容增 大，高电位附近的峰电容减小。 3 种不同孔径分布的微孔型多孔炭作电极的 EDLC 的循环伏安特性受浸溃时间影 响的程度也不同。 关键词:多孔炭;双电层电容器;循环伏安法;微于L; 电容特性 中固分类号: TQ424. 1 文献标识码:A Capacitance characteristic of porous carbon electrodes with micropores studied by cyclic voltammetry ZHANG Lin , LIU Hong-bo (College of Materials Science and Engineering , Hunan University , Changsha 410082 , China) Abstract: Three porous carbons with different micropore distribution , prepared from phenolic resins activation by various mass fraction of KOH , were applied in electric double-layer capacitor (EDLC). The BET specific surface ar eas and pore structure parameters of three porous carbons obtained were determined by the nitrogen gas adsorption isotherm. And the capacitance charicteristics of EDLC used three porous carbons were studied by cyclic voltammetry (CV). The results show that the cyclic voltammogram of the EDLC used porous carbons with micropore appears ca- pacitance peak near high voltage (::f:: 1. 0 V) after arriving capacitance flat at small scan rate , which is different