城市生活垃圾热解特性TG_DSC分析.pdfVIP

53 7 Vol. 5 3 7 2002 7 Journal of Chemical Industry and Engineering ( China) July 2002 TG- DSC 李 季 张 铮 杨学民 姚建中 林伟刚 ( , 00080) X 705 A 0438- 57 (2002) 07- 0759- 06 TG- DSC STUDY ON PYROLYSIS CHARACTERISTICS OF MUNICIPAL SOLID WASTES LI Ji, ZHANG Zheng, YANG Xuemin, YAO Ji nzhong nd LIN Weig ng ( M ult i - p h ase R eac tion L abor ator y , I nst it ute of P rocess E ng ineer ing , Ch inese A cade my of S ciences , B ei ing 00080, Ch ina) Abstr ct Seven typical components in municipal solid w astes ( MSWs) paper, food, textile, wood, straw , plastic and rubber w ere chosen as the thermogravimetric analysis samples in this paper to study the pyrolysis characteristics. By the thermogravimetry and differential scanning calorimetry (TG- DSC) analysis, pyrolysis characteristics of M SWs! components and pyrolysis endothermal enthalpy were obtained. The kinetic parameters of pyrolysis were determined w ith the Doyle method and a multi- stage first order pyrolysis model w as proposed. The simulated results by this model show ed good agreement w ith the T G experimental data. T he pyrolysis characteristics provide significant parameters to a new concept of circulating fluidized bed incinerator, w hich can simultaneously restrain the high- temperature HCl corrosion and emission of dioxins. Keywords M SWs, thermogravimetry, differential scanning calorimetry, pyrolysis characteristics, kinetic parameters , 引 言 , [ ~ 5] . , , , , . 2000 7 T