碳纤维增强碳复合材料高温抗氧化硅基陶瓷涂层研究进展_英文_.pdfVIP

第38 卷第5 期 硅 酸 盐 学 报 Vol. 38 ，No. 5 2 0 1 0 年 5 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY M a y ，2 0 1 0 碳纤维增强碳复合材料高温抗氧化硅基陶瓷涂层的研究进展 韩敏娜，郭领军，李克智，李贺军 (西北工业大学碳/碳复合材料工程技术研究中心，西安 710072) 摘 要：碳纤维增强碳(carbon fiber reinforced carbon，C/C)复合材料抗氧化问题一直是国际材料界研究的热点。硅基陶瓷作为C/C 复合材料抗氧化涂 层，是目前研究最深入的涂层体系。综述了国内外近几年 C/C 复合材料高温抗氧化硅基陶瓷涂层的研究进展，总结了C/C 复合材料高温抗氧化硅基 陶瓷涂层的制备工艺和对已有工艺的改进方法，分析了硅基陶瓷涂层在高温空气中、燃烧环境中的氧化失效机理。结合硅基非氧化物陶瓷(SiC，Si N 3 4 等)环境障碍涂层的发展，展望了C/C 复合材料在复杂环境中抗氧化涂层的研究方向。 关键词：碳/碳复合材料；硅基陶瓷涂层；抗氧化 中图分类号：TB332 文献标志码：A 文章编号：0454–5648(2010)05–0991–06 RESEARCH PROGRESS ON HIGH TEMPERATURE OXIDATION PROTECTIVE SILICON-BASED CERAMIC COATINGS FOR CARBON FIBER REINFORCED CARBON COMPOSITES HAN Minna，GUO Lingjun，LI Kezhi，LI Hejun (C/C Composites Technology Research Center, Northwestern Polytechnical University, Xi’an 710072, China) Abstract: The oxidation resistance for carbon fiber reinforced carbon (C/C) composites has been one of the popular research topics in materials field. Up to now, silicon-based ceramics are the most thoroughly studied materials as the oxidation protective coatings for C/C composites. The recent achievement of high temperature oxidation protective silicon-based ceramic coatings of C/C composites at home and abroad is reviewed. The preparation technologies and improvements of high temperature oxidation protective sili- con-based ceramic coatings of C/C composites are introduced. The oxidation mechanisms of silicon-based ceramic coatings in high temperature air and in combustion environment are discussed. According t