天然石墨球_热解炭核壳结构制备及电化学性能的研究_英文_.pdfVIP

第 23卷 　第 1期 新 　型 　炭 　材 　料 Vo l. 23　No. 1 　 2008年 3月 N EW CARBON MA TER IAL S M ar. 2008 　 A rticle ID : ( 2008) 0 1003007 Improv ing the electrochem ica l properties of na tura l graph ite spheres by coa ting w ith a pyrolytic carbon shell L IU Shu h e, 　Y IN G Zh e, 　W AN G Zuo m ing, 　L I Feng, 　BA I Shu o, 　W EN L e i, 　CH EN G H u im ing (S heny ang N a tiona l L abora tory f orM a teria ls S cience, Institu te of M eta l R esea rch, Ch inese A cadem y of S ciences, S heny ang 110016, Ch ina) A b stract: 　Tw o k inds of m od if ied na tu ra l g rap h ite (M N G ) sp heres w ith a p y ro ly tic carbon she ll on sm ooth o r g ranu lar su rface w ere ob ta ined u sing f lu id ized bed chem ica l vap or dep os ition of ace ty lene by adju sting the reac tion p aram eters. The core of the M N G has a h igh ly ordered grap h ite struc tu re and the she ll has a d iso rdered struc tu re. C om p ared w ith na tu ra l g rap h ite (N G ) sp heres, M N G w ith a co reshe ll structu re show s im p roved f irst cyc ling eff ic iency and cyc lab ility. Esp ec ia lly, the M N G sp heres w ith a granu lar su rface p ossess 84 % re ten tion of the f irst d ischarge cap ac ity after 4 1cyc les, ow ing to effec tive dec rease of the con tac t res istance and inc rease of con tact area betw een the M N G sp heres. Keywords: 　F lu id ized bed chem ica l vap or dep os ition; C o reshe ll struc tu re; Py ro ly tic carbon; M od if