硫酸介质中2-氨基-5-苯基-1,3,4-噻二唑对碳钢的缓蚀作用.pdfVIP

22 5 Vol.22 No.5 2010 9 CORROSION SCIENCE AND PROTECTION TECHNOLOGY Sep. 2010 2- -5- -1,3,4- Æ , , , , 210009 : 2- -5- -1,3,4- (APT) 0.5mol/L . , APT , , APT , Æ, Langmuir , . : ; ; ; : TG174.42 : A : 1002–6495(2010)05–0431–04 Inhibition of 2-Amino-5-Phenyl-1,3 ,4-Thiadiazole on Mild Steel in H2 SO4 Media YANG Xiao-yuan, TANG Yong-ming, YANG Wen-zhong, WAN Rong College of Science, Nanjing University of Technology, Nanjing 210009 Abstract: 2-Amino-5-phenyl-1, 3, 4-thiadiazole (APT) has been studied as an inhibitor for corrosion of mild steel in 0.5 mol/L H2 SO4 using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The electrochemical measurements indicate that the compound acts as a mixed type inhibitor and the mechanism of adsorption on mild steel is chemisorption. The spontaneous adsorption of APT is found to obey the Langmuir adsorption isotherm. Key words: inhibitor; mild steel; polarization curves; electrochemical impedance , APT , H O , 2 [1]. , . . 1,3,4- SN APT : , , 250 mL , 0.1 mL 0.1 mL , , . Azhar , 0∼5 0.3 mL , 15 min [2] 2,5- (n– )-1,3,4 . 4 h, 50 mL , 1 mol/LHCl 0.5 mol/L H SO 50% NaOH PH 8∼9, , , 2 4 , , , , 75.8%, 2- -5- -1,3,4- . : 223∼226 ; : C% 54.19, H% 4.01, N%