腐殖酸论文：光谱法分析环境水样的研究.docVIP

腐殖酸论文：光谱法分析环境水样的研究 【中文摘要】随着全球经济的飞速发展,污染问题日益严重,环境水质状况更是受到人们的关注。溶解有机质(DOM)广泛存在于环境水体中,对水环境污染程度有着重要影响,而荧光特性又是其重要的光学性质。腐殖酸是溶解有机质中的主要组分,本论文运用三维荧光光谱法对标准腐殖酸样品进行分析,得到其三维荧光指纹谱图,并依据谱图中荧光峰位置、数量、强度的变化讨论了pH值和样品浓度对其荧光特性的影响；再通过发射荧光光谱法、同步荧光光谱法、三维荧光光谱法对环境水样进行分析,并将结果对比得出相关结论,为环境水质污染程度的判别提供依据。 【英文摘要】With the rapid development of the global economy, the problem of pollution becomes more serious and the quality of water has attracted much attention. Dissolved organic matter (DOM) that has a significant impact on the level of pollution is widely present in environmental water, and the fluorescence is an important optical property of them. Humic acid is the main component of dissolved organic matter (DOM). we analyzed the humic acid samples with the three-dimensional fluorescence spectroscopy and obtain their spectra of fingerprints. We discussed the dependence of fluorescent characteristics on the pH values and concentrations based on the differences of peak抯 position, number and intensity; then we analyzed water samples through fluorescence spectroscopy, synchronous fluorescence spectroscopy, three-dimensional fluorescence spectrometry and compared the results to draw relevant conclusions which provide the basis for distinguishing the degree of environmental water pollution. 【关键词】腐殖酸 三维荧光光谱 荧光发射光谱 环境水样 【英文关键词】humic acid three-dimensional fluorescence spectra Fluorescence spectroscopy Environmental water samples 【目录】光谱法分析环境水样的研究 摘要 4-5 ABSTRACT 5 目录 6-7 第一章 绪论 7-10 1.1 引言 7 1.2 环境水样中的溶解有机质 7-9 1.3 研究目的及主要工作 9-10 第二章 荧光光谱技术 10-22 2.1 荧光发光机理 10-11 2.2 荧光的激发光谱和发射光谱 11-12 2.3 荧光寿命和荧光量子产率 12-13 2.4 影响荧光强度的因素 13-16 2.5 荧光与分子结构的关系 16 2.6 溶液荧光猝灭 16-17 2.7 荧光分析法 17-20 2.8 荧光分析仪器 20-22 第三章 腐殖酸三维荧光光谱特性 22-37 3.1 腐殖质简介 22-24 3.2 实验仪器与试剂 24-26 3.3 实验操作 26 3.4 实验结果分析 26-36 3.5 小结 36-37 第四章 环境水样荧光光谱分析 37-47 4.1 实验样品与仪器 37-38 4.2 实验结果 38-45 4.3 小结 45-47 第五章 结论 47-48 致谢 48-49 参考文献 49-50