固相微萃取（SPME）技术基本理论及应用进展.pdfVIP

综述与评论 固相微萃取（SPME ）技术基本理论及应用进展 1,2 1 1 2 周珊 赵立文 马腾蛟 黄骏雄 (1 北京市疾病预防控制中心 北京 100013) (2 环境化学与生态毒理国家重点实验室中科院生态环境研究中心 北京 100085) 摘 要 固相微萃取SPME 作为一种新型的样品前处理技术，自1989 年加拿大Waterloo 大学的学者Pawliszyn 发 明以来得到了迅速发展。本文介绍了SPME 技术基本理论，讨论了该技术的影响因素及操作要点，综述了SPME 技术 应用进展，重点综述SPME 与各种分析仪器联用在环境和食品分析领域的应用研究进展。 关键词 固相微萃取（SPME ）；环境分析；食品分析 中图分类号 O651 Fundamental Theory of SPME Technology and its Application Progress 1,2 1 1 2 Zhou Shan , Zhao Liwen , Ma Tengjiao , Huang Junxiong 1 ( Beijing Municipal Center for Disease Prevention and Control, Beijing 100013, China) (2 State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China) Abstract As a new type of sample pretreatment technology, solid-phase microextraction (SPME), since its invention in 1989 by Pawliszyn and his associates in Waterloo University, Canada, has been developed rapidly over the years. Fundamen- tal theory of SPME technology was introduced, influential factors and operation key points were discussed. In addition, application progress was reviewed, focus was put on coupling SPME with various of analytical instrumentation and its application in field of environmental and food analysis. Key words SPME; environmental analysis; food analysis 1 SPME技术基本理论 n = Kfs ·Vf ·C0 (2) 也就是说萃取纤维涂层所能吸附的待测物质的量 1.1 基本理论 与其