二苯基噻吩活性氧量子产率_杀虫活性及稳定性研究_陈小军.pdfVIP

2006,39(1):81-87 Scientia Agricultura Sinica 510642 : α-α- ∆α- ∆α- µ· µ· µ· µ· α- α- Study on Active Oxygen Quantum Yield, Insecticidal Activities and Stability of Diphenylthiophene CHEN Xiao-jun, XU Han-hong, WANG Yu-jian, HU Shan, ZHANG Zhi-xiang, ZHANG Yao-mou (Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, Laboratory of Insect Toxicology, South China Agricultural University, Guangzhou 510642) Abstract: ObjectiveActive oxygen quantum yield, insecticidal activities and stability of diphenylthiophene were compared to α-terthienyl in a study for the first time.ResultThe results showed that absorbency variety max of diphenylthiophene was 0.438 after ultraviolet irradiation for 280 min while α-terthienyl absorbency variety max was 0.480 after ultraviolet irradiation for 200 min. LC -3 -1 -4 50 value of diphenylthiophene and α-terthienyl against 3rd instar larvae of Aedes albopictus was 9.1810 µg·ml and 9.6910 µg·ml-1 after 24 h of treatment. LC50 value of the two pesticides against 3rd instar larvae of Plutella xylostella was 267.87 µg·ml-1 and 222.22 µg·ml-1 after 24 h of treatment. The half-life of diphenylthiophene and α-terthienyl in methanol was 113.62 h and 10.49h. Quantum yield of diphenylthiophene and α-terthienyl was almost identical and they all had high toxicity to Aedes albopictus and Plutella xylostella, but diphenylthiophene was stable than α-terthienyl. ConclusionIt is concluded that diphenylthiophene has avoided the deficiency of photoactivated insecticides which degraded quickly in the environment and could not