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聚乳酸低密度聚乙烯共混聚合物的制备及表征.pdf
中国印刷与包装研究 2013年第5期 (第5卷) 论文摘译
CHINA PRI】nNG AND PACKAG玎 G STUDY V01.05No.5 2013.1O PAPERSDIGEST
Poly(1acticacid)/LowDensityPolyethylenePolymerBlends:
PreparationandCharacterization
Author KOTIBA Hamad,MOSAB Kaseem ,FAWAZ Deri
DepartmentofChemistry,FacultyofScience,LaboratoryofMaterialsRheology(LMR),UniversityofDamascus,Damas—
CHS,Syria
AbstractPoly(1acticacid)(PLA)wasmeltblendedwithlowdensitypolyethylene(LDPE)withtheaimofreplacingcorn—
moditypolymersinfutureapplications.BecausecostofPLA isquitehigh,itisnoteconomicallyfeasibletouseitalonefor
day todayuseasapackagingmaterialwithoutblending.Inthiswork,PLA wasblendedwithLDPE indifferentratiosbyU—
singalaboratoryscalesinglescrew extruder.Thepreparedblendswerechraacterizedintermsofrheologicalandmechanical
properties.Rheological propertieswerestudiedusingacapillaryrheometer,andtheBagley’Scorrectionwasperfomr ed.True
shearrate(,,),trueshearstress(7_),trueviscosity(叩)andnon—Newtonianindex(n)weredetermined.Therelation—
shipbetweentrueviscosityandtemperaturewasalsostudied,andtheflowactivationenergyataconstnatshera stress(E )
wasdetermined.Themechanicalpropertiesoftheblendswereinvestigatedondogbone—shapedsamplesobtainedbyinjection
molding,tensiletestswereperformedusingTestometricM 350—10KN ,stressatbreak,strainatbreka andYoung’Smodulus
weredetermined.Rheological resultsshow incompatibilitybetweenthetwopolymerswherethetureviscosityoftheblend
decreasedwithincreasingPLA contentbelow thelineofmi xingrule,alsoitwasfoundthattheblendexhibitsshear—thinning
behavioroverthernageofthestudied shearrates.Themechna ical resultsalsoshowed incompatibilitybetweenPLA nad
LDPE intheblend,wherestressatbreka andYoung’SmodulusoftheblendincreasedwithincreasingPLA content,whereas
strainat breakoftheblendswassimilra tothatofneatPLA.
KeywordsBiodegradable;PLA;LDPE;Polymerblends;Rheology;
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