含钒石煤钒钾镁硫酸浸出相关性研究.docVIP

含钒石煤钒钾镁硫酸浸出相关性研究 蒋谋锋张一敏包申旭杨晓 摘要对某云母型含钒石煤硫酸浸出过程中钒、钾、镁的浸出相关性进行研究。结果表明，钒、钾、镁具有很好的共生关系，主要赋存于云母类矿物中，部分镁赋存于方解石中。低温下，以游离态的高价钒浸出为主，钒钾、钒镁的浸出相关性均较差，而高温下，以晶格束缚态的低价钒浸出为主，钒钾、钒镁均呈现出很好的浸出相关性。硫酸浓度对钒、钾、镁的浸出相关性影响较小，95 ℃，不同硫酸浓度下钒钾、钒镁均具有很好的浸出相关性。含镁方解石在硫酸中溶解速率较快，同等条件下，镁的浸出率高于钒钾。 关键词石煤钒钾镁相关性TF841.3 文献标志码：A 文章编号：1007-7545（2014）11-0000-00 Relevant Research on Sulfuric Acid Leaching of V, K and Mg from Vanadium-bearing Stone Coal JIANG Mou-feng, ZHANG Yi-min, BAO Shen-xu, YANG Xiao (College of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China) Abstract：Relevancy of V, K and Mg in sulfuric acid leaching process was investigated to uncover leaching mechanism of vanadium for mica-type vanadium-bearing stone coal. The results show that V, K and Mg have close symbiotic relationship in mica mine, with part of magnesium occurring in calcite. At low temperature, both vanadium-potassium and vanadium-magnesium show a poor leaching correlation, and leaching of dissociative high valence vanadium is prevailing. At high temperature, both vanadium-potassium and vanadium-magnesium present a good leaching correlation, and leaching of low valence vanadium trapped in lattice is prevailing. Concentration of sulfuric acid has less effect on relevancy of V, K and Mg, and both vanadium-potassium and vanadium-magnesium have a good leaching correlation under different concentration of sulfuric acid at 95 ℃. Under the same condition, leaching rate of magnesium is higher than that of potassium and vanadium due to a faster dissolution rate of magnesium-bearing calcite in sulfuric acid. Key words：stone coal; sulfuric acid leaching; vanadium; potassium; magnesium; correlation 石煤是我国一种独特的含钒资源，广泛分布于四川、湖南、湖北等地[1]。钒在石煤中品位较低，大多以三价或四价的形式取代六八面体夹心层中的铝以类质同象的形式赋存于云母类矿物中，很少以游离态或吸附态的五价钒形式存在于风化石煤中[2]，提取难度较大。酸浸提钒工艺[3-1]具有浸出率高对原矿适应性强等优点，但是，其选择性差，浸出钒的同时，大量钾、镁、铝等杂质元素也一同浸出。石煤酸浸提钒的关键在于使云母晶格中不溶或难溶的低价钒转化为水溶性或酸溶性的高价钒由于钾、镁、铝均为主要的云母组成元素，因此，研究其浸出规律可以更全面钒的浸出机理。目前仅何东升[1]和张小云[1]对石煤酸浸过程中钒、铝的浸出关系进行了初步探讨，而钒