重氮化反应 氨基变卤素 p-FLUOROBENZOIC ACID.pdfVIP

Organic Syntheses, Coll. Vol. 2, p.299 (1943); Vol. 13, p.52 (1933). p -FLUOROBENZOIC ACID [Benzoic acid, p -fluoro-] Submitted by G. Schiemann and W. Winkelmüller. Checked by W. W. Hartman, J. R. Byers, and J. B. Dickey. 1. Procedure In a 5-l. round-bottomed flask are placed 165 g. (1 mole) of ethyl p -aminobenzoate (Note 1), 300 cc. of water, and 204 cc. (2.5 moles) of concentrated hydrochloric acid (sp. gr. 1.19). This mixture is wa