反应萃取结晶制备碳酸钙与氯化氢过程研究.pdfVIP

第十一届全国博士生学术年会 反应萃取结晶制备碳酸钙和氯化氢过程研究 李云钊 宋兴福 陈贵兰 于建国 ( 国家盐湖资源综合利用工程技术研究中心 华东理工大学资源与环境工程学院，上海 200237) 摘要：索尔维制纯碱法会产生大量主要成分为氯化钙的蒸氨废液，一直未得到充分的资源化利用。本课题研发一种 新的处理工艺，选用 N235-异戊醇为萃取体系，通过反应萃取结晶过程，将氯化钙溶液转变为碳酸钙产品和氯化氢气 体。实验结果表明，在反应时间为 240 分钟、反应温度为 20 ℃、氯化钙初始浓度为 1 mol/L、搅拌速率为 200rpm、 N235 的体积分数为 50%、油水相比为 2:1 的条件下，氯化钙的转化率可达到 75% 以上，有机相中氢离子浓度可达0.70 mol/L 左右并得到菱形六面体的方解石型碳酸钙。同时运用 FTIR 、XRD 、SEM 等表征手段对产品进行表征。有机叔 胺的萃取机理为离子缔合机理，并通过饱和法测得萃合物的组成为 R3N ·HCl 。总反应的焓变ΔH = -36.47 kJ/mol，为 放热反应，升高温度不利于反应的进行。 关键词： 蒸氨废液；N235 ；反应萃取结晶； The Preparation of CaCO3 and HCl via the Reaction-extraction-crystallization Process LI Yun-Zhao, SONG Xing-Fu, CHEN Gui-Lan ,YU Jian-Guo (National Engineering Research Center for Integrated Utilization of Salt Lake Resource, School of Resource and Environment Engineering, East China University of Science and Technology, Shanghai 200237) Abstract: Amounts of distiller waste mainly containing calcium chloride are being produced in the Solvay process, which has not been recycled completely yet. A new treatment route was developed in this subject, in which CaCl2 solution was transformed into CaCO3 and HCl via a reaction-extraction-crystallization process using N235-isoamyl alcohol as the extraction system. Experiment results showed that the best condition is that reaction time is 240 min, temperature is 20℃, the initial concentration of CaCl2 is 1 mol/L, stirring rate is 200 rpm, the volume fraction of N235 is 50% and the phase ratio is 2:1. In this condition, the + conversion of CaCl2 is up to 75%, the concentration of H in organic phase is about 0.70 mol/L and the calcite can be obtained. The products were char