Fe掺杂TiO2薄膜磁学性质研究的论文.pdfVIP

Fe掺杂TiO2薄膜磁学性质研究 徐建萍1,2 李岚1,3张晓松1,2 1天津理工大学材料科学与工程学院，天津3003842天津市光电显示材料与器件重点 实验室，天津3003843显示材料与光电器件省部共建教育部重点实验室，天津300384 摘要：缺陷是影响稀磁半导体(DMS)铁磁性的重要因素。本文采用溶胶-凝胶方法制备Fe掺杂TiO2薄膜， 600℃真空烧结。X射线衍射发现样品呈现单一锐钛矿相，没有发现与Fe有关的其他相和磁性颗粒。X射线电 子能谱显示样品中Fe以三价离子形式存在。O离子以两种形式存在：Ti-O和H-O，说明真空条件烧结在样品 表面产生了缺陷。电学性质测试发现电阻呈现半导体特性。磁性测试表明Fe掺杂TiO2薄膜具有室温铁磁性， ZFC/FC测试排除磁性颗粒存在。实验结果表明Fe掺杂锐钛矿相TiO2薄膜样品，缺陷的存在有利于Fe离子之 间的铁磁交换作用。 关键词：稀磁半导体；缺陷；铁磁性 InvestigationofmagneticpropertiesofFe-dopedTiO2films XUJianping1,2 LILan1,3 ZHANGXiaosong1,2 1SchoolofMaterialsScienceEngineering,TianjinUniversityofTechnology,Tianjin 300384,China;2KeyLaboratoryofDisplayMaterialsPhotoelectricDevices(TianjinUniversityof Technology),MinistryofEducation,Tianjin300384,China;3TianjinKeyLaboratory forPhotoelectricMaterialsDevices,Tianjin300384,China Abstract:Defectsisanimportantfactortoeffecttheferromagnetismofdilutedmagneticsemiconductors.Fe-doped TiO2filmsarefabricatedbysol-gelspincoatingandannealedat600℃ invacuum.X-raydiffractionmeasurements revealthatalldiffractionpeakscanbeattributedtoTiO2withanatasephasestructure.Nosegregatedphasesand magneticparticlespresentinthesampleswithinXRDdetectionlimit.X-rayphotoelectronspectroscopyshowsiron elementexistsintheionformwithatervalentstate.ThespectrumofO1scanbeattributedtoO2-ionsinTi-Oband andsurfacehydroxylgroups(H-Oband),respectively,indicatingthatsurfacedefectsmightbegeneratedinthe filmsafterannealinginvacuum.Thefilmsshowasimilarbehaviorforresistivity.Thehysteresisloopsindicatethat Fe-dopedanataseTiO2filmsareferromagneticatroomtemperature.ZFC/FCcurvesarerathersmoothandnosignal peaksarefoundinthemeasuredtemperaturerange,indicatingabsenceofanymagneticnanoparticlesorothermag neticphasesinthefilms.TheseobservationssuggestthatdefectsareenergeticallyfavorableforthelongrangeFe3+- Fe3+ferromagneticcouplinginFe-dope