英文：由污泥灰转化成氢气过程中：热化学处理中对重金属转化的影响因素.pdfVIP

Available online at Waste Management 28 (2008) 2709–2722 /locate/wasman Sewage sludge ash to phosphorus fertiliser: Variables influencing heavy metal removal during thermochemical treatment H. Mattenberger a, G. Fraissler a, T. Brunner a,d,*, P. Herk b, L. Hermann a,c, I. Obernberger a,d a Austrian Bioenergy Centre GmbH, Inffeldgasse 21b, 8010 Graz, Austria b ARP GmbH, Johann Sacklgasse 65-67, 8700 Leoben, Austria c ASH DEC Umwelt AG, Donaufelderstrasse 101/4/5, 1210 Wien, Austria d BIOS BIOENERGIESYSTEME GmbH, Inffeldgasse 21b, 8010 Graz, Austria Accepted 3 January 2008 Available online 10 March 2008 Abstract The aim of this study was to improve the removal of heavy metals from sewage sludge ash by a thermochemical process. The resulting detoxified ash was intended for use as a raw material rich in phosphorus (P) for inorganic fertiliser production. The thermochemical treatment was performed in a rotary kiln where the evaporation of relevant heavy metals was enhanced by additives. The four variables investigated for process optimisation were treatment temperature, type of additive (KCl, MgCl2) and its amount, as well as type of reac- tor (directly or indirectly heated rotary kiln). The removal rates of Cd, Cr, Cu, Ni, Pb, Zn and of Ca, P and Cl were investigated. The best overall removal efficiency for Cd, Cu, Pb and Zn could be found for the indirectly heated system. The type of additive was critical, since MgCl2