荷兰TU-e 招国家公派博士生, 欢迎申请.docVIP

荷兰TU/e 招国家公派博士生， 欢迎申请 如有问题，请联系： kyan@ 或 io@tue.nl ? 项目1-2：? “Mico Flow Chemistry and Process Technology” ? Topic title: Experimental research of plasma assisted propane reforming Name supervisor: Prof. V. Hessel E-mail address: V.Hessel@tue.nl ? Summary The plasma assisted propane reforming will be carried out in a simple-structured glid-arc discharge reactor in this project. Propane reforming by using oxygen and steam will both be investigated. The optimal operating conditions for synthesis gas production as well as the kinetics of the reaction system will be studied. Besides?plasma reforming by itself, the synergetic effect ofapplying both plasma and heterogeneous catalysts will be investigated in order to gain insight into their interaction and improved performance. The energy efficiency will be evaluated and optimized by studying different operating conditions as mentioned above. ? Topic title: High-c, T Biphasic Flow Processing of D-Fructose to HMF and Levulinic Acid Name supervisor: Prof. V. Hessel E-mail address: V.Hessel@tue.nl ? Summary The conversion of cellulose-glucose-fructose-HMF presents a central pathway in the emerging biomass chemistry field and probably one with highest chances for use of micro process technology. In this context, a biphasic flow processing of D-Fructose to HMF and levulinic acid with HCl/CH2Cl2 (following Chem.Commun., 2012, online) shall be developed and optimized, in particular concerning the multi-phase mass transfer. The common aim to work at high concentrations (high-c) will be followed; moreover, it will be tested if other harsh process conditions such as high temperature (high-T) (or high pressure, high-p) are beneficial as well. This involves also finding smart solutions for the reaction medium such as the use of MIBK as environmental friendly solvent, effective extracting agent with green profiles (following ChemSusChem 5, 2012,383) and phase modifiers to facilitate phase separation and prevent side reactions (following