聚碳酸酯型水性聚氨酯分散体的合成与性能研究.pdfVIP

WATER-BORNE RESIN 聚碳酸酯型水性聚氨酯分散体的 合成与性能研究 1 2 1 2 □ 朱延安 ,张心亚 ,曹树潮 ,陈焕钦 (1.广东嘉宝莉化工有限公司,广东江门 529085；2.华南理工大学化工与能源学院,广州 510641) 摘要：采用聚碳酸酯二元醇Desmophen C与TDI合成了水性聚氨酯分散体。拉伸试验结果表明,乳胶 膜具有优异的拉伸强度(高达60 MPa)和断裂伸长率(高达600％)。研究了软段分子量、软段用量对聚碳 酸酯聚氨酯力学性能和微观相分离结构的影响。结果表明,随着软段用量的增加,乳胶膜的断裂强度 迅速下降,断裂伸长也有所下降。不同分子量的聚碳酸酯也具有相同的规律。但相同软段用量,随着 分子量的增加,断裂强度并没有下降,反而有所上升,且断裂伸长略有下降。同时聚碳酸酯型水性聚氨 酯乳胶膜具有优异的水解稳定性。 关键词：聚碳酸酯；聚氨酯；分散体；力学性能 中图分类号：TQ630.4+95 文献标识码：A 文章编号：1006-2556(2008)07-0031-04 Synthesis and performance study on water-borne polycarbonate-based PU dispersion Zhu Yan’an Zhang Xinya, Cao Shuchao, Chen Huanxin (Guangdong Carpoly Chemical Co., LTD., Jiangmen 529085, Guangdong Province; College of Chemical and Energy, South China University of Technology, Guangzhou 510641, Guangdong Province) Abstract: Water-borne PU dispersion is synthesized from polycarbonate diols Desmophen C and TDI. Tensile test results show that the latex i lm is of excellent tensile strength (as high as 60MPa) and elongation at break (as high as 600%). The inl uence of soft segment molecule weight, soft segment content on the mechanical performance and microscopic phase separation structure of polycarbonate-based PU, showing that with the increasing of soft segment usage, breaking strength of the latex i lm quickly decreases and the elongation at break also decreases in some degree, and polycarbonate with dif erent molecule weight following the same law; but at the same usage of soft segment, with the increasing of molecule weight, the breaking strength doesn’t decrease, and instead, increases in some degree, and the elongation at break decreases a little; in the some time, the water-borne polycarbonate-based PU is of excellent hydrolytic stability. Keywords: polycarbonate, PU, dispersion, mechanical performance 0 前 言 结合,利用其分子结