焙烧层状氢氧化镁铝对溴离子吸附性能研究.pdfVIP

4 36 2 赵正鹏, 王海增, 郭鲁钢, 邓培昌, 邢 坤, 朱培怡, 宋卫得 , 266100 : 研究了500 下焙烧层状氢氧化镁铝对溴离子吸附性能, 考察了吸附时间吸 附剂用量吸附温度吸附初 pH 值等条件对吸附性能的影响实验结果表明, 焙烧层状氢 氧化镁铝对溴离子具有较好的吸附性能, 35 下饱和吸附量为 133. 33m g/g, 其吸附等温线可 以用 L angm uir等温方程描述 : 层状氢氧化镁铝; 溴离子; 吸附; 焙烧 : TQ123. 7 : A : 1673- 6850 2007 02- 0004- 04 Ad orption of Brom ideAn ion By Calcined Layered Double Hydroxide ZHAO Zhengpeng, WANG H aizeng, GUO Lugang, DENG Peichang, X ING Kun, ZHU Peiyi, SONG W eide College of Chem i try and Chem icalEngineering, O cean U niver ity of Ch ina, Q ingdao Shandong 266003, Ch ina A bstrac t: In thi paper, the ad orp tion capab ility of brom ide an ion on calcined LDH ha been tud ied. T he effect of reaction tmi e, do age, temperatu re and the pH value of brom ide an ion on the ad orption hav e been inve tigated. T he re u lt how that the calc ined LDH ha an excellent per form ance in ad orb ing brom ide anion, the ad orption capac ity i 133. 33mg /g at 35 and in accord ance w ith the L angmu ir i otherm. K ey w ord s: layered double hydrox ide ; brom ide an ion; ad orption; calc ination , , - , , B r [ 1] 1t !, [ 2 ] 10t , , , Layered Double Hydrox ide , LDH , , [ 3~ 6] 1 , 1. 1 仪器和试剂 1. 1. 1 , 302, , ; 232, , , ; SHA - C - [ 7] - - [ 8 ] F Cl I ; pH S - 3C : 2006 - 09- 21 : 1982- , , : 座机电话号码 36 2 5 ; - ; IKA , , , Ba ic ; DZF ; ; SHZ 2 - ; 2. 1 X 射线衍射 析 D /M ax - rBX 1XRD, 1. 1. 2 2 , ; , , ; ; 2 , , ; , 1. 2 实验方法 1. 2. 1 500kg / , 11. 1m, 2 81. 4m / g, 1 XRD 0. 47mL / g 2 500 3h 3, , XRD, 1: 4h, 500 3h , , , 1. 2. 2 X X CuK, 40kV, 90mA, 7 /m in , X , X 1. 2. 3 [ 9 ] 2 XRD , 50mL, 10 ? 10- 5m ol/L20 ? 10- 5 m ol/L30 ? 10- 5 m ol/L40 ? 10- 5 m ol/L50 ? 10- 5 m ol/L60 ? 10- 5 m ol/L70 ? 10- 5m ol/L80 ? 10- 5 m ol/L 8 100mL , 2mL 5m ol/L T I SAR , 3 XRD , , 3 , XRD, 2 E , - logC C E , 1. 2. 4 , , 100m L , 100mL , ! , , 6 36 2 , 2. 2 溴离子标准曲线 - logC C E , 4, 2 - logC 0. 0179E + 2. 8565, R 0. 9998, 6 2. 5 温度对吸附的影响 0.