微孔聚四氟乙烯增强复合质子交换膜研究.pdfVIP

21 78 化 学 进 展 Vol. 21 No. 78 2009 8 PROGRESS IN CHEMISTRY Aug. , 2009 微孔聚四氟乙烯增强复合质子交换膜研究* 1,2 1 1* * 1 2 李 雷 尚玉明 谢晓峰 冯少广 蒋金芝 ( 1. 清华大学核能与新能源技术研究院 北京100084; 2. 中 大学化学化工学院 长沙410083) 质子交换膜燃料电池( PEMFC) 由于具有能量转化率高环保等特点而受到广泛关注作为质 子交换膜燃料电池核心组件之一的关键材料质子交换膜( PEM) 成为燃料电池研究的热点聚四氟乙烯 (PTFE) 微孔膜由于具有高的化学和尺寸稳定性, 被用来作为复合质子交换膜的增强基底本文对当前微孔 PTFE 增强复合质子交换膜的研究进展进行了综述, 介绍了微孔PTFE 与全氟类离子树脂部分含氟类离子树 脂和非氟类离子树脂等的复合情况, 着重说明各种复合增强的类型和方式, 并比较了复合改性前后各种膜的 物性特点, 最后展望了微孔PTFE 复合增强膜的未来研究趋势 聚四氟乙烯微孔膜 增强 质子交换膜 燃料电池 : TB383; TM911. 4 : A : 1005-281X( 2009) 078- 1611-08 Development of Porous-PTFE Reinforced Proton Exchange Membranes 1, 2 1 1* * 1 2 L i L ei Shang Yuming X ie Xiaof eng Feng Shaoguang Jiang Jinz hi ( 1. Institute of Nuclear and New Energy Tec nology, Tsing ua University, Beijing 100084, C ina; 2. College of C emistry and C emical Engineering, Central Sout University, C angs a 410083, C ina) Abstract PEMFC as attracted broad attention due to t e ig energy efficiency and environmental benefits. As t e key components of t e PEMFC, special attention is paid to t e researc of proton exc ange membranes. Porous-PTFE ( polytetrafluoroet ylene) as been used as substrate in t e preparation of reinforced proton exc ange membranes due to its excellent c emical and dimensional stability to satisfy t e requirement of PEMFC. T is paper reviews recent progress of porous-PTFE reinforced proton exc ange membranes. T e types, met ods of preparing and related properties of t e PTFE reinforced proton exc ange membranes are discussed in detail. T e development trend of t is kind of membranes is prospected.