甲酸钠液相氧化工艺地研究.pdfVIP

甲酸钠液相氧化工艺的研究 1 1 1 1 1,2 黄光斗 张智 李柯 龙化云 胡兵 (1湖北工业大学化学与环境工程学院，湖北 武汉 430068 2 武汉理工大学材料学院，湖北 武汉 430074) 摘要：以碳酸氢钠和碳酸钠为催化体系合成季戊四醇是一应用前景广阔的绿色新工艺。其中，将母 液中副产物甲酸钠液相氧化为碳酸氢钠和碳酸钠，使之循环利用，是一关键步骤。本文以 Pd-Cu/C 为催化剂，对甲酸钠这一液相氧化工艺进行了单因素和正交实验研究。实验结果表明最佳工艺条件 为：甲酸钠33.3g ，物料浓度10%，温度130℃，压力0.5MPa ，反应时间6h，催化剂用量2g 。在优 化反应条件下进行甲酸钠液相催化氧化反应时，甲酸钠转化率为97.3% 。 关键词：甲酸钠 液相 氧化 催化 Study on the Process of Liquid-phase Oxidation of Sodium Formate 1 1 1 1 1,2 HUANG Guang-dou , ZHANG Zhi , LI Ke , LONG Hua-yun ,Hu Bing (1 College of Chemical and Environmental Engineering, Hubei University of Technology,Wuhan 430068 2 College of Material Science and Engineering,Wuhan University of Technology,Wuhan 430074 ) Abstract: The new synthetic technology of pentaerthyritol with Na CO and NaHCO as catalyst is a green 2 3 3 process of wide application prospect. The liquid-phase oxidation of sodium formate to Na2CO3 and NaHCO3 is very important for consummating the new synthetic technology of pentaerthyritol. The optimum experimental conditions of the process of liquid-phase oxidation are investigated through factor analyses and orthogonal design experiment with Pd-Cu/C as catalyst. They are listed as following: the quantity of sodium formate is 33.3g, the initial concentration is 10%, the temperature is 130℃, the pressure is 0.5MPa, the time is 6h and the quantity of catalyst is 2g. The experimental result shows in the case of the optimum conditions, the conversion of sodium formate is 97.3%. Keywords: sodium formate, liquid-phase, oxidation, catalysis 季戊四醇是一种重要的有机化工产品。在涂料、润滑