蓖麻油生物柴油的减压蒸馏及气-质谱分析.pdfVIP

2011年第36卷第8期 中凿油脂 生物紫油 蓖麻油生物柴油的减压蒸馏及气一质谱分析 靳福全，孟丽君，王晶聂，李霞，刘 强 (太原工妲学院化学与化工系，太原030008) 摘要：分别以浓硫酸和氢氧化钠为催化刹，以蓖麻油和甲醇为原料削备了生物柴油榉品，并对其进 行了减匾蒸馏。用气一质联月仪对蒸馏样品进行了分析。结装表明：由蓖麻油剃毒孚的生物柴油主 要成分为蓖麻酸甲酯，还含有少量油酸甲酯、亚油酸甲酯、十六酸甲酯及十八酸甲酯等成分；当减压 蒸馏的液相温度较高、升温速率较慢时，少部分蓖麻酸甲酯将分解为lO一十一烯酸甲酯和庚醛；当 减压蒸馏的生物柴油样品含硫酸催化荆时，大部分蓖麻酸甲酯将发生脱水反应生成亚油酸甲酯。 关键词：蓖麻油；生物柴油；减压蒸馏；气一质谱分析 文献标志码：A 文章编号：1003-7969(2011)98—0069-05 中圈分类号：TQ645；TK63 andGC／MS ofcastorbiodiesel Vacuumdistillation analysis JIN Xia，LIU Fuquan，MENGLijaN，WANGJingjing，LI Qiang and of of Chemical Institute Chemistry Engineering，TaiyuanTechnology， (Department 030008，China) Taiyuan and sulfuricacid weremadefromcastorseedoil methanolconcentrated Abstract：Biodiesel samples using and asa vacuumdistillationofbiodiesel werecarried sodium hydroxidecatalystrespectively，and samples were GC／MS．Theresultsshowedthatmain oftllebiodie— out．Distillated samplesanalyzedby components selfromcastorseedoilwere werestilla of addition，there methylricinoleate，in spotmethyloleate，methyl and octadecanoate．Whenthe of was hexadecanoate linoleate，methyl methyl temperatureli