N-(4%2c6-二甲氧基嘧啶-2-基)-N%27-(乙氧酰基)硫脲金属配合物的比热容和热力学性质.pdfVIP

N-(4,6-二甲氧基嘧啶-2-基)-N-( 乙氧酰基)硫脲金属配 合物的比热容和热力学性质 1 1∗ 1 1,2 1 张杜蓓 任莹辉 傅丁薇 宋纪蓉 徐抗震 1．西北大学化工学院，陕西省物理无机化学重点实验室 西安 710069 2 ．故宫博物院文保科技部 北京 100009 摘要： 运用Micro-DSCⅢ微热量仪对N-(4,6-二甲氧基嘧啶-2-基)-N-( 乙氧酰基)硫脲与CuCl2 所形成的金属配合物进行比热容测定，在所测温度范围284~344 K 内，比热容与温度的关系 -2 -5 2 -1 -1 式为：Cp=-2.712+2.160×10 T-2.792×10 T J·g ·K 。根据测定的比热容方程，计算出了此配 合物以298.15 K为基础在284~344 K温区的热力学函数：焓、熵和吉布斯自由能。 关键词： 酰基硫脲；金属配合物；比热容；热力学性质 中图分类号： 0642 文献标识码：A 文章编号： Special Heat Capacity and Thermodynamic Properties of a Copper( Ⅱ) Compound Constructed by N-(4,6-Dimethoxylpyrimidin)-N’-(ethoxycarbonyl)thiourea 1 1 1 ZHANG Dubei REN Yinghui FU Dingwei SONG Jirong1,2 XU Kangzhen1 1. Department of Chemical Engineering, Northwest University, Shaanxi Key Laboratory of Physico-inorganic Chemistry, Xi’an 710069 ； 2. Conservation Technology Department, the Palace Museum, Beijing 100009 Abstract: The specific heat capacity of a Copper( Ⅱ) Compound Constructed by N-(4,6-Dimethoxylpyrimidin)-N ’-(ethoxycarbonyl)thiourea was determined with continuous Cp mode of mircocalorimeter(Micro-DSCⅢ). In the determining temperature ranged from 283 K to 353 K, the relationship between the specific heat capacity of the componud and the -2 -5 2 -1 -1 thermodynamic temperature was Cp=-2.712+2.160×10 T-2.792×10 T J·g ·K . Using the dete