三维炭纤维预制体孔隙模型与气体传质计算.pdfVIP

第 39 卷第 2 期 中南大学学报自然科学版( ) Vol.39 No.2 2008 年 4 月 J. Cent. South Univ. (Science and Technology) Apr. 2008 三维炭纤维预制体孔隙模型与气体传质计算 熊 翔，龙 莹，肖 鹏 ( 中南大学 粉末冶金国家重点实验室，湖南 长沙，410083) 摘 要：通过建立三维正交结构炭纤维预制体宏观孔隙网络结构几何模型和化学气相渗透(CVI)工艺过程中反应 气体在孔隙网络中的数学传质模型，研究预制体的孔隙网络结构对 CVI 工艺过程中气体的比渗透率和复合材料最 终致密度的影响。研究结果表明：三维正交结构炭纤维预制体的宏观孔隙结构在空间上可以看成是由呈周期性排 列的体心立方“晶胞”构成；X ，Y 和 Z 3 个方向纤维束直径大小及比例关系决定三维正交结构炭纤维预制体宏观 孔隙网络的结构和形状，也是决定反应气体在孔隙中的比渗透率和复合材料最终致密度的重要因素；当 X ，Y 和 Z 3 个方向纤维束直径的比例关系一定时，不同预制体在 CVI 增密过程中比渗透率随孔隙率变化的趋势相同；复 合材料的最终致密度一定；比渗透率随纤维束直径增大而略有增大。 关键词：化学气相渗透(CVI) ；气体传质；孔隙网络模型；比渗透率；致密度 中图分类号：TB332 文献标识码：A 文章编号：1672-7207(2008)02−0209−07 Modeling of pore structures and calculation of gas transport for three dimensional carbon fabric structure perform XIONG Xiang, LONG Ying, XIAO Peng (State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China) Abstract ：On the base of the establishment of the geometry model of the three dimensional orthogonal woven carbon fabric structure perform and the relative calculation model of reactant gases transportation during the chemical vapor infiltration (CVI) processing, effects of the pore structure of the performs on the permeability of reactant gases and the densification of the composites were studied. The results show that the microscopical pore structure of the three dimensional orthogonal woven carbon fabric structure perform is composed of body-centered cubes which arranged periodically at spaces. The net structure and shape of the pores of perform are det