优势产氢-产酸发酵类型的建立及比较.pdfVIP

优势产氢 - 产酸发酵类型的建立及比较 宋佳秀 任南琪 段志杰 （哈尔滨工业大学市政环境工程学院，哈尔滨 150090 ） 摘要 利用两套连续流搅拌槽式生物制氢反应器（CSTR ），采用优化的启动参数，实现了优势产 氢 产酸发酵类型（乙醇型和丁酸型）的启动和稳定运行；计算两者的投碱量，发现维持丁酸型发酵所 消耗的碱是维持乙醇型发酵的7 倍；在稳定运行阶段，在相同进水COD 负荷情况下，两个反应器的 产气及产氢能力基本相当，日产氢量在11. 3 ~ 14 . 5 L 范围内，而丁酸型发酵的生物持有量为乙醇型 的1. 8 倍，而乙醇型发酵菌群的比产氢速率要高于丁酸型，分别为平均21. 2 moi/ （kgVSS ·d ）和11. 1 moi/ （kgVSS ·d ）。试验证明，乙醇型发酵菌群具有更宽的pH 耐受幅，因此对环境的适应能力更强。 关键词 生物制氢 氢经济 比产氢速率 荧光原位杂交 Establishment and comparation for the predominant hydrogen production-acidogenic fermentation types Song Jia-xiu ，Ren Nan-gi ，Duan Zhi-jie （School of Municip al Enuironmental Engineering ， Harbin Institute of Technology ，Harbin 150090 ，China ） Abstract ：Two predominant hydrogen production and acidogenic fermentation types startup and opera- tion were reaiized successfuiiy in certain pH by adjusting iniet aikaiinity in two CSTRs. By caicuiating the amounts of aikaiinity during steady operation ，it was found that the consumed aikaiinity for maintaining bu- tyric acid fermentation was seven times than that for ethanoi fermentation. In this stage ，with the same iniet COD ioading the amounts of gas production and hydrogen production were simiiar about 11. 3 ~ 14 . 5 L/ d. The biomass in butyric acid fermentation reactor was accounted about 1. 8 times more than that in ethanoi fermentation reactor. As a resuit ，the specific hydrogen production rate for ethanoi fermentation was 21. 2 moi/ （kgVSS ·d ）averageiy and the other was 11. 1 moi/ （kgVSS ·d ）averageiy. The resuit showed ethanoi fermentative microfiora was more adaptabie with pH extent and its ambient. Keywords ：Hydrogen production ；Hydrog