利用荧光屏探测器质谱方法研究邻位二氯苯的电子贴附解离.pdfVIP

CHINESE J0URNAL 0F CHEM ICALPHYSICS V0LUME 27．NUM BER 6 DECEM BER 27，2014 ARTICLE DissociativeElectronAttachmentto 1．2一DichlorobenzeneusingMass SpectrometrywithPhosphorScreen Chuan-jinXuan，Xu—dongWang，LeiXia，BinWu，HaoLi，Shan—xiTian NationalLaboratory forPhysicalSciencesattheMicroscaleandDepartmentofChemicalPhysics UniversityofScienceandTechnologyofChina，Hefei230026，China (Dated：ReceivedonAugust5．2014；AcceptedoffSeptember23，2014) Anion massspectrometry isdeveloped onthebasisofourhome—madeanionvelocitymap imagingapparatus．TheC1一 productefficiencycurvefordissociativeelectron attachment to1,2一dichlor0benzeneisobtainedrfom 0．2eV to8eV．meanwhiletheslicedimagesofthis anion arerecorded at1．2and 6．0eV correspondingtotwopeakpositionsoftheproduct efficiencycurve． Keywords： Dissociativeelectronattachment，1，2一Dichlorobenzene，Anionmassspectrom— etry I．INTR0DUCT10N includingthephosphorscreendetector(imagingAPD— P20，PHOTONIS，Inc．)inourapparatus[5]，andthe Dissociative electron attachment fDEA1 is a see— DEAof1,2一dichlorobenzene(1,2一C6H4C12)isinvesti— gatedwithanionmassspectrum andVM Iexperiments． ondary process of ionization radiation damages to biomolecules．butplaysanimportantroleinthechem— icalbond cleavegesf1}． In thisprocess temporary I1．EXPERIM EN。r_AL DEVEL0PM ENT negativeion，fAB)一，istheessentialintermediateand can spontaneously decay through the dissociation to AsshowninFig．1，theanionsignalsofDEAaretrans— A and B— fragments．Information abouttheproduc— form ed to the multiplication electronsvia