Au_Si基底上电沉积Pt纳米层的衰减全反射表面增强红外吸收光谱_英文_.pdfVIP

( ) 第 43 卷 　第 4 期 复旦学报 自然科学版 Vol . 43 No . 4 2004 年 8 月 Journal of Fudan U niver sit y (N at ural Science) Aug . 2004 　　Article ID :04277 104 (2004) AttenuateTotalReflection Surfaceenhanced Inf rared Absorption Spectroscopy on Pt Nano layers Electrodeposited on a Au/ Si Substrate 1 1 1 1 YAN Yangang , HUO Shengj uan , L I Qiaoxia , MA Min , 1 1 2 GUO Zhanhe , CAI Wenbin , O SAWA Ma sato shi ( 1. Chem is t ry Dep art ment , Fudan University , S hang hai 　200433 , China ; 2 . Catalysis R esearch Center , Hokk aido University , S app oro 　060 0811, J ap an) Abstract : Surfaceenhanced infrared absorption sp ectra of CO have been obtained on Pt nanolayers prop erly electrode posited onto a Au/ Si substrate wit h t he Kret schmann attenuatetotalreflection (A TR) configuration . The overall in tensity in reflectance for t he linearly adsorbed CO band is enhanced by a factor of around 10 , comp ared to t he corre sponding t heoretical maximum values for bulk metal surfaces wit h t he external infrared reflection and absorption sp ec troscop y ( IRA S) . In comp arison to t he socalled abnormal infrared effect s (A IR Es) in t he literature ,