不同矿点凹凸棒黏土对复合高吸水性树脂吸水性能的影响_陈红.pdfVIP

第34卷第1期 非金属矿 Vol.34 No.1 年 月 2011 1 Non-Metallic Mines January, 2011 不同矿点凹凸棒黏土对复合高吸水性树脂吸水性能的影响 1,2 1 1 陈 红   王文波  王爱勤 （1 中国科学院兰州化学物理研究所，甘肃 兰州 730000 ；2 中国科学院研究生院，北京 100049） 摘  要 以不同矿点凹凸棒黏土为无机组分，采用溶液聚合法制备了羧甲基纤维素钠接枝聚丙烯酸/ 凹凸棒黏土(CMC-g-PAA/APT) 复合高 吸水性树脂。用红外光谱和扫描电镜表征了凹凸棒黏土和复合高吸水性树脂的结构和形貌，研究了凹凸棒黏土组成对复合高吸水性树脂吸水性能 的影响。结果表明，含有较低铝离子凹凸棒黏土制备的复合高吸水性树脂具有较高的吸水倍率，含有较高铝离子和钙离子凹凸棒黏土制备的复合 高吸水性树脂具有较好的反复溶胀性能。 关键词 高吸水性树脂 凹凸棒黏土 吸水倍率 吸水速率 成分 O636;O69;TQ041 A 1000-8098(2011)01-0001-04 中图分类号： 文献标识码： 文章编号： Effect of Attapulgite from Different Zone on Water Absorbency of Superabsorbent Composites Chen Hong1,2 Wang Wenbo1 Wang Aiqin1 (1 Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000; 2 Graduate University of the Chinese Academy of Sciences, Beijing 100049) Abstract A series of carboxymethyl cellulose-g-poly(acrylic acid)/attapulgite superabsorbent composites were prepared by free-radical solution polymerization, using attapulgite from different zone as the inorganic additives. The structure and morphologies of attapulgite and their composites were characterized by FTIR spectra and SEM techniques. The composition of attapulgite and their effects on the water absorbency of the composites were investigated. The results indicated that the superabsorbent composite based on attapulgite with the lower content of Al3+ had best water absorbency, and attapulgite with the higher content of Al3+ and Ca2+ had best re-swelling abilities. Key words superabsorbent attapulgite water-absorbency swelling rate composition 高吸水性树脂是一种具有优越吸水