CuCoMn-zeolite双功能催化剂转化生物质基合成气制取液态烃.pdfVIP

CHINESE J0URNAL oF CHEMICAL PHYSICS V0LUM E 27．NUMBER 5 0CT0BER 27．2O14 ARTICLE ConversionofBio-·syngasto LiquidHydrocarbonoverCuCoM n-·Zeolite BifunctionalCatalysts ZhaoxiaZhang．Pei—yanBj．Pei—wenJiang．Quan—xinLj DepartmentofChemicalPhysics．AnhuiProvinceKeyLaboratoryofBiomassCleanEnergy,University ofScienceandTechnologyofChina，Hefei230026，China (Dated：ReceivedonMay6，2014；AcceptedonMay29，2014) A seriesofbifunctionalcatalystscomposedofacomponentforhigheralcoholsynthesis(Cn— CoMnoxidesCCM1andanacidiczeolitefSAP0—34，ZSM一5，Y，MCM一41)wereprepared ofrproduction ofliquidhydrocarbondirectly from abio—syngasthrough aone—stagepro— cess．Theeffectsofzeolitetypezeolitecontent，Si／A1ratioandpreparationmethodon catalysttextureand itsreaction performancewereinvestigated．Higherselectivitiesand yieldsofliquidproductswereobtainedbyusingbifunctionalcatalysts．Theyieldsofliquid hydrocarbonsdecreasedintheorderCCM—ZSM一5CCM—SAPO一34CCM—YCCM—MCM一 41．CCM—zSM一5(20wt％，Si／Al=100)preparedbycoprecipitationmethoddisplayedthe optimalcatalyticperofrmancewiththehighestCO conversion f76％)andyieldofliquid products(30％)．ThecatalystswerecharacterizedbyN2adsorption／desorption，NH3一TPD， XRD ．andH2-TPR analysis．Theresultsshowedthathigherspecificsurfaceareasandpore volumesofbifunctionalcatalystswereachievedbyaddingzeolitesintoCuCoMnprecursors． Medium poredimensionandmoderateacidityinCCM ．ZSM一5wereobserved．whichproba- blyresultedinitsexcellentreaction performance．Additionally,ahighernumberofweaker acidsitesfweakand／ormedium acidsites1wereofrmedbyincreasingZSM一5contentin CCM—ZSM一5ordecreasingSi／A1ratioinzSM一5．Itwasalsoseenthatmetaldispersionwas higherandreducibility ofmetalionswaseasieron theCCM—ZSM一5catalystpreparedby coprecipitation．Thehigheralcohols—to—hydrocarbon processpr