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蛇纹石与滑石的同步抑制原理
卢毅屏,张明洋,冯其明,欧乐明,张国范
(中南大学 资源加工与生物工程学院,湖南长沙 410083)
摘要:通过浮选试验沉降实验电位,蛇纹石和滑石结果表明在pH范围内蛇纹石与滑石表面电性相反,发生异相凝聚蛇纹石与滑石关键词:蛇纹石;滑石;分散;中图分类号:TD91 文献标识码:A ync suppression principle of serpentine and talc
LU Yi-Ping, ZHANG Ming-Yang, FENG Qi-Ming, OU Le-Ming, ZHANG Guo-Fan
(School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China)
Abstract: Sync suppressing multi-magnesium silicate minerals by flotation from refractory and low grade nickel sulfide ores is a common method. In this paper, with sodium hexametaphosphate and guar gum as regulators, sync suppression and mechanism of serpentine and talc were studied by flotation tests, sedimentation tests, Zeta potential measurements and adsorption measurements. The results show that surface potential of serpentine and talc particles was contrast in a wide pH range, which lead to heteroaggregation between serpentine and talc particles, which made lowing magnesium in sulfide ore flotation process more difficult. Serpentine and talc was sync suppressed and separated from artificial mixed mineral of pyrite with sodium hexametaphosphate and guar gum. Sodium hexametaphosphate made the surface potential of serpentine particles from the positive into negative, which resulted in serpentine and talc particles dispersed and increased the adsorption of guar gum on talc surface. The study put forward this sync suppression principle that heteroaggregation between serpentine and talc particles should be eliminated firstly, then easy floating minerals were suppressed.
Key words: serpentine; talc; dispersion; suppression
在硫化铜镍矿浮选中,镁始终是选矿难。][][][]。蛇纹石、滑石橄榄石辉石][],更使得降镁难度增大。
蛇纹石滑石研究,蛇纹石通过,并防止其在有用矿物表面形成矿泥罩盖][][][]。而对于滑石进入精矿],主要有三种途径分离滑石与硫化矿:一是预先脱泥除去微细粒滑石;预先浮选滑石再浮选硫化矿添加抑制剂滑石然后浮选硫化矿通常是预先滑石,再添加有机抑制剂抑制滑石浮选硫化矿,实现硫化矿和滑石的分离][][]。到目前为止,硫化铜镍矿浮选研究蛇纹石与滑石为硫化铜镍矿浮选中含镁硅酸盐矿物分离提供。1.1 试样与药剂
蛇纹石取自江苏东海,块矿经锤碎手选后用瓷球磨、搅拌磨磨细,得到90%粉末粒径小于10μm蛇纹石矿样。滑石取自广西桂林,得到90%粉末粒径小于μm滑石矿样。-0150mm+0.037mm黄铁矿矿样。
所用试剂中HCl、NaOH、六偏磷酸钠、古尔胶
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