碱石灰烧结法处理粉煤灰工艺探索.pdfVIP

碱石灰烧结法处理粉煤灰工艺探索 王 刚 （中国铝业山东分公司，山东淄博 255051 ） 摘要：本文所述为采用碱浸、碱石灰烧结法处理粉煤灰，提取其中的铝、硅用于化学品氧化铝生产的工艺探索。 通过试验提出了该工艺最佳条件：将粉煤灰在苛性钠:100g/l 碱液、L/S:3～5、95℃、2h 条件下碱活化处理提高其 有效A/S,碱液循环浸出增浓；经活化的高铝粉煤灰用碱石灰烧结法处理，经过烧结、脱硅等工序处理后得到氧化 铝浓度：70g/l±、硅量指数：A/S ＞380 的精液用于生产化学品氧化铝，碱浸脱硅液在循环增浓后得到模数 1.0 左 右的低模数水玻璃，与化学品生产相嫁接，节能减排、实现资源的综合利用。 关键词：有色金属冶金；粉煤灰；碱石灰烧结；脱硅 The Technology of Extract Alumina from Fly Ash with Alkali Lime Sintering WANG Gang （Shandong Branch of Chalco, Zibo, Shandong, 255051, China ） Abstract: To study on the optimize condition of extracting alumina and silicon from fly ash with alkali leaching and soda-lime sintering to produce alumina chemicals, this paper offeres a technic that fly ash is activation by alkali dissolution with Na O concentration to 100g/l, and the rate of liqior to solid is 2 K 3~5, optimum dissolve temperature is 95℃, reaction time hold two hours. In the whole procedure,alkali concentration in solution is increased when circulaing several times .Then the fly ash is process to pure sodium aluminates’ solution that concentration of [Al O ]=70g/l, the ratio of alumina to silicon is 2 3 [A/S] 380 by sinering and deep desiliconization of soda-lime sintering technics.It could produce alumina chemicals from the pure solution, and soluble glass with a solution module keep at one is worked out by increasing concentration of silicon and sodium. Consequently, this program can produce qualified products by soda-lime sintering with fly ash as raw material .The paper also proposed sev