混合导体致密膜反应器中高温密封材料的制备及表征.pdfVIP

30 5 ( ) V o l. 30 N o. 5 200 8 9 JOURNAL O F NAN J ING UN IV ERS ITY OF TECHNOLOGY ( N atural Sc ence Ed t on) Sep. 2008 张志诚, 张 春, 常先锋, 董学良, 金万勤 ( 南京工业大学 化学化工学院, 材料化学工程国家重点实验室, 江 南京 210009) : 开发了一种适合膜反应器高温密封的陶瓷密封剂, 其主要由基料S O 填料固化剂及陶瓷粉组 . 通过正 2 交试验法优化了陶瓷密封剂各组分的配比, 借助于热膨胀仪及扫描差示量热仪分析了密封剂的热膨胀系数和软化 温度. 在混合导体透氧膜反应器中考察了密封剂在还原性气氛下的密封性能. 结果表明, 所制备的陶瓷密封剂用于 氧渗透及CH 部分氧化( POM )反应的高温密封时, 具有良好的密封效果, 膜反应器稳定运行320 h后不泄漏. 4 : 管式膜; 高温; 陶瓷; 密封剂* : TQ4 33. 5 : A : 167 1- 7627 ( 2008) 05- 0012- 04 P reparation and characterization of h ightem perature sealan t for m ix edcondu cting den se m em brane reactors ZHANG Zh cheng, ZHANG Chun, CHANG X anfeng, DONG Xuel ang, JIN W anq n ( Sta te K ey Labo ra tory o f M ate r alsO r ented Chem ca l Eng neer ng, Co llege of Chem stry and Chem cal Eng nee r ng, N anj ng U n ve rs ty o f T echno logy, N an j ng 210009, Ch na) Abs tract: A ceram c sea lant w as deve loped for the h ghtem perature seal ng n the m xedconduct ng m embrane re actors. T h s sea lant cons sted of S O , f ll ngs, so l d fy ng reagent, and ceram c pow ders. T he compos t on o f the 2 sea lant w as optm zed by the orthogona l experm ents, and ts therm al expans on coeff c ent and soften ng tem pera ture w ere analyzed by the d latom eter and d fferent a l scann ng ca lor m eter, respect vely. T he seal ng perform ance for reduc ng atm ospheresw as character zed on the m xedconduc ng