N_C_2H_5_3HCl_2ZnCl_2离子液体催化十二烷基苯的氯甲基化反应研.pdfVIP

) 2007 4 A CT A P ET RO LEI SIN ICA P ET RO LEU M P R OCE SSIN G S ECT IO N) 23 2 : 100187 19 2007) N( C2 H5 )3 HCl2ZnCl2 STUDY ON BLANC CHLOROMETHYLATION OF DODECYLBENZENE CATALYZED BY ZnCl2 IONIC LIQUID 王 雨, 郑晓宇, 吴肇亮 WA N G Y u, ZH EN G X iaoyu , WU Z haoliang , 102249) ( S tat e K ey L aborat or y of H eav y Oi l P rocess i ng , China Univ ers i ty of P et role um, Be ij ing 102249, Chi na) : N C H ) H Cl2ZnCl G m 2 5 3 2 msm , s ) , 55 n ) n ) n ) n Gmsm ) = 1 3 1. 6 0 . 0 1 10 h, 98% , G , N C H ) HCl2ZnCl , 12612 2 5 3 2 , : N C H ) HCl2ZnCl ; ; ; 2 5 3 2 : O 643 : A Abstra t: Dodecylbenzyl chlo ride was synt hesized u sing maincat alyst o f m oist urest able N C2 H 5 ) 3 H Cl2ZnCl2 io nic liquid and phaset ransf ercat alyst of cat ionic Gemini surf act ant s Gmsm w her e s is t he spacer leng th and m the tail leng t h in hy drocarbo n g roups) . T he select iv it y o f ndodecylbenzy l chloride w as up to 98% under the opt imal react io n co ndition of t emperat ure 55 , n Dodecy lbenzene) n P araf orm aldehy de) n ZnCl2 ) n Gmsm ) = 1 3 1. 6 0. 01, and react io n tim e 10 h. Mo re